| 1 | Sat 14 Aug 2021 | 211-4 v Real MadridAlavés 1-4 Real Madrid | Spanish La Liga |
| 2 | Wed 22 Sep 2021 | 210-1 v EspanyolEspanyol 1-0 Alavés | Spanish La Liga |
| 3 | Sat 25 Sep 2021 | 211-0 v Atlético MadridAlavés 1-0 Atlético Madrid | Spanish La Liga |
| 4 | Fri 1 Oct 2021 | 210-1 v Athletic BilbaoAthletic Bilbao 1-0 Alavés | Spanish La Liga |
| 5 | Tue 26 Oct 2021 | 211-0 v ElcheAlavés 1-0 Elche | Spanish La Liga |
| 6 | Sat 30 Oct 2021 | 211-1 v BarcelonaBarcelona 1-1 Alavés | Spanish La Liga |
| 7 | Sat 6 Nov 2021 | 212-1 v LevanteAlavés 2-1 Levante | Spanish La Liga |
| 8 | Sat 20 Nov 2021 | 212-2 v SevillaSevilla 2-2 Alavés | Spanish La Liga |
| 9 | Sat 27 Nov 2021 | 21 1-2 v Celta VigoAlavés 1-2 Celta Vigo | Spanish La Liga |
| 10 | Fri 3 Dec 2021 | 211-2 v GranadaGranada 2-1 Alavés | Spanish La Liga |
| 11 | Sat 11 Dec 2021 | 21 1-1 v GetafeAlavés 1-1 Getafe | Spanish La Liga |
| 12 | Sat 18 Dec 2021 | 210-2 v Rayo VallecanoRayo Vallecano 2-0 Alavés | Spanish La Liga |
| 13 | Tue 21 Dec 2021 | 212-5 v VillarrealVillarreal 5-2 Alavés | Spanish La Liga |
| 14 | Sun 2 Jan 2022 | 211-1 v Real SociedadAlavés 1-1 Real Sociedad | Spanish La Liga |
| 15 | Sun 9 Jan 2022 | 210-0 v Athletic BilbaoAlavés 0-0 Athletic Bilbao | Spanish La Liga |
| 16 | Tue 18 Jan 2022 | 210-4 v Real BetisReal Betis 4-0 Alavés | Spanish La Liga |
| 17 | Sun 23 Jan 2022 | 210-1 v BarcelonaAlavés 0-1 Barcelona | Spanish La Liga |
| 18 | Sat 5 Feb 2022 | 211-3 v ElcheElche 3-1 Alavés | Spanish La Liga |
| 19 | Sat 16 Apr 2022 | 211-0 v Rayo VallecanoAlavés 1-0 Rayo Vallecano | Spanish La Liga |
| 20 | Tue 19 Apr 2022 | 211-2 v MallorcaMallorca 2-1 Alavés | Spanish La Liga |
| 21 | Sat 30 Apr 2022 | 212-1 v VillarrealAlavés 2-1 Villarreal | Spanish La Liga |
| 22 | Sat 7 May 2022 | 210-4 v Celta VigoCelta Vigo 4-0 Alavés | Spanish La Liga |
| 23 | Wed 11 May 2022 | 212-1 v EspanyolAlavés 2-1 Espanyol | Spanish La Liga |
| 24 | Sun 22 May 2022 | 210-1 v CádizAlavés 0-1 Cádiz | Spanish La Liga |
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