| 1 | Sat 14 Aug 2021 | 31-4 v Real MadridAlavés 1-4 Real Madrid | Spanish La Liga |
| 2 | Sat 21 Aug 2021 | 3 0-1 v MallorcaAlavés 0-1 Mallorca | Spanish La Liga |
| 3 | Sat 18 Sep 2021 | 3 0-2 v OsasunaAlavés 0-2 Osasuna | Spanish La Liga |
| 4 | Wed 22 Sep 2021 | 3 0-1 v EspanyolEspanyol 1-0 Alavés | Spanish La Liga |
| 5 | Sat 25 Sep 2021 | 31-0 v Atlético MadridAlavés 1-0 Atlético Madrid | Spanish La Liga |
| 6 | Fri 1 Oct 2021 | 30-1 v Athletic BilbaoAthletic Bilbao 1-0 Alavés | Spanish La Liga |
| 7 | Mon 18 Oct 2021 | 30-1 v Real BetisAlavés 0-1 Real Betis | Spanish La Liga |
| 8 | Sat 23 Oct 2021 | 32-0 v CádizCádiz 0-2 Alavés | Spanish La Liga |
| 9 | Tue 26 Oct 2021 | 31-0 v ElcheAlavés 1-0 Elche | Spanish La Liga |
| 10 | Sat 30 Oct 2021 | 3 1-1 v BarcelonaBarcelona 1-1 Alavés | Spanish La Liga |
| 11 | Sat 6 Nov 2021 | 32-1 v LevanteAlavés 2-1 Levante | Spanish La Liga |
| 12 | Sat 20 Nov 2021 | 3 2-2 v SevillaSevilla 2-2 Alavés | Spanish La Liga |
| 13 | Sat 27 Nov 2021 | 3 1-2 v Celta VigoAlavés 1-2 Celta Vigo | Spanish La Liga |
| 14 | Sat 11 Dec 2021 | 31-1 v GetafeAlavés 1-1 Getafe | Spanish La Liga |
| 15 | Sat 18 Dec 2021 | 3 0-2 v Rayo VallecanoRayo Vallecano 2-0 Alavés | Spanish La Liga |
| 16 | Tue 21 Dec 2021 | 32-5 v VillarrealVillarreal 5-2 Alavés | Spanish La Liga |
| 17 | Sun 2 Jan 2022 | 31-1 v Real SociedadAlavés 1-1 Real Sociedad | Spanish La Liga |
| 18 | Sun 9 Jan 2022 | 3 0-0 v Athletic BilbaoAlavés 0-0 Athletic Bilbao | Spanish La Liga |
| 19 | Tue 18 Jan 2022 | 30-4 v Real BetisReal Betis 4-0 Alavés | Spanish La Liga |
| 20 | Sat 5 Feb 2022 | 31-3 v ElcheElche 3-1 Alavés | Spanish La Liga |
| 21 | Sun 13 Feb 2022 | 32-1 v ValenciaAlavés 2-1 Valencia | Spanish La Liga |
| 22 | Sat 19 Feb 2022 | 30-3 v Real MadridReal Madrid 3-0 Alavés | Spanish La Liga |
| 23 | Sat 26 Feb 2022 | 32-2 v GetafeGetafe 2-2 Alavés | Spanish La Liga |
| 24 | Fri 4 Mar 2022 | 3 0-0 v SevillaAlavés 0-0 Sevilla | Spanish La Liga |
| 25 | Sun 13 Mar 2022 | 30-1 v Real SociedadReal Sociedad 1-0 Alavés | Spanish La Liga |
| 26 | Sat 19 Mar 2022 | 32-3 v GranadaAlavés 2-3 Granada | Spanish La Liga |
| 27 | Sat 2 Apr 2022 | 31-4 v Atlético MadridAtlético Madrid 4-1 Alavés | Spanish La Liga |
| 28 | Sun 10 Apr 2022 | 30-1 v OsasunaOsasuna 1-0 Alavés | Spanish La Liga |
| 29 | Sat 16 Apr 2022 | 3 1-0 v Rayo VallecanoAlavés 1-0 Rayo Vallecano | Spanish La Liga |
| 30 | Tue 19 Apr 2022 | 31-2 v MallorcaMallorca 2-1 Alavés | Spanish La Liga |
| 31 | Sat 30 Apr 2022 | 3 2-1 v VillarrealAlavés 2-1 Villarreal | Spanish La Liga |
| 32 | Wed 11 May 2022 | 32-1 v EspanyolAlavés 2-1 Espanyol | Spanish La Liga |
| 33 | Sun 15 May 2022 | 31-3 v LevanteLevante 3-1 Alavés | Spanish La Liga |
| 34 | Sun 22 May 2022 | 30-1 v CádizAlavés 0-1 Cádiz | Spanish La Liga |
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