| 1 | Sun 13 Aug | 241-2 v Real BetisVillarreal 1-2 Real Betis | Spanish La Liga |
| 2 | Fri 18 Aug | 241-0 v MallorcaMallorca 0-1 Villarreal | Spanish La Liga |
| 3 | Sun 27 Aug | 243-4 v BarcelonaVillarreal 3-4 Barcelona | Spanish La Liga |
| 4 | Fri 1 Sep | 24 1-3 v CádizCádiz 3-1 Villarreal | Spanish La Liga |
| 5 | Thu 21 Sep | 24 0-2 v PanathinaikosPanathinaikos 2-0 Villarreal | UEFA Europa League Group F |
| 6 | Wed 27 Sep | 241-2 v GironaVillarreal 1-2 Girona | Spanish La Liga |
| 7 | Sat 30 Sep | 24 0-0 v GetafeGetafe 0-0 Villarreal | Spanish La Liga |
| 8 | Thu 5 Oct | 24 1-0 v RennesVillarreal 1-0 Rennes | UEFA Europa League Group F |
| 9 | Sun 8 Oct | 241-2 v Las PalmasVillarreal 1-2 Las Palmas | Spanish La Liga |
| 10 | Sun 15 Oct | 31-0 v NorwayNorway 0-1 Spain | European Championship Qualification Group A |
| 11 | Sun 22 Oct | 24 1-1 v AlavésVillarreal 1-1 Alavés | Spanish La Liga |
| 12 | Sun 26 Nov | 243-1 v OsasunaVillarreal 3-1 Osasuna | Spanish La Liga |
| 13 | Thu 30 Nov | 243-2 v PanathinaikosVillarreal 3-2 Panathinaikos | UEFA Europa League Group F |
| 14 | Sun 3 Dec | 24 1-1 v SevillaSevilla 1-1 Villarreal | Spanish La Liga |
| 15 | Wed 6 Dec | 24 0-0 v Maccabi HaifaVillarreal 0-0 Maccabi Haifa | UEFA Europa League Group F |
| 16 | Sat 9 Dec | 24 0-3 v Real SociedadVillarreal 0-3 Real Sociedad | Spanish La Liga |
| 17 | Sun 17 Dec | 241-4 v Real MadridReal Madrid 4-1 Villarreal | Spanish La Liga |
| 18 | Wed 20 Dec | 243-2 v Celta VigoVillarreal 3-2 Celta Vigo | Spanish La Liga |
| 19 | Sat 13 Jan | 240-3 v Las PalmasLas Palmas 3-0 Villarreal | Spanish La Liga |
| 20 | Mon 1 Apr | 241-2 v Atlético MadridVillarreal 1-2 Atlético Madrid | Spanish La Liga |
| 21 | Sun 14 Apr | 241-1 v Athletic BilbaoAthletic Bilbao 1-1 Villarreal | Spanish La Liga |
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