| 1 | Sun 20 Aug | 14-1 v Mainz 051 FC Union Berlin 4-1 Mainz 05 | German Bundesliga |
| 2 | Sat 26 Aug | 14-1 v Darmstadt 98Darmstadt 98 1-4 1 FC Union Berlin | German Bundesliga |
| 3 | Sun 3 Sep | 10-3 v RB Leipzig1 FC Union Berlin 0-3 RB Leipzig | German Bundesliga |
| 4 | Sat 16 Sep | 11-2 v VfL WolfsburgVfL Wolfsburg 2-1 1 FC Union Berlin | German Bundesliga |
| 5 | Wed 20 Sep | 10-1 v Real MadridReal Madrid 1-0 1 FC Union Berlin | UEFA Champions League Group C |
| 6 | Sat 23 Sep | 10-2 v 1899 Hoffenheim1 FC Union Berlin 0-2 1899 Hoffenheim | German Bundesliga |
| 7 | Sat 30 Sep | 10-1 v 1 FC Heidenheim1 FC Heidenheim 1-0 1 FC Union Berlin | German Bundesliga |
| 8 | Tue 3 Oct | 12-3 v Sporting Braga1 FC Union Berlin 2-3 Sporting Braga | UEFA Champions League Group C |
| 9 | Sat 7 Oct | 12-4 v Borussia DortmundBorussia Dortmund 4-2 1 FC Union Berlin | German Bundesliga |
| 10 | Sat 21 Oct | 10-3 v VfB Stuttgart1 FC Union Berlin 0-3 VfB Stuttgart | German Bundesliga |
| 11 | Tue 24 Oct | 10-1 v Napoli1 FC Union Berlin 0-1 Napoli | UEFA Champions League Group C |
| 12 | Sat 28 Oct | 10-2 v Werder BremenWerder Bremen 2-0 1 FC Union Berlin | German Bundesliga |
| 13 | Sat 4 Nov | 10-3 v Eintracht Frankfurt1 FC Union Berlin 0-3 Eintracht Frankfurt | German Bundesliga |
| 14 | Wed 8 Nov | 11-1 v NapoliNapoli 1-1 1 FC Union Berlin | UEFA Champions League Group C |
| 15 | Sun 12 Nov | 1 0-4 v Bayer 04 LeverkusenBayer 04 Leverkusen 4-0 1 FC Union Berlin | German Bundesliga |
| 16 | Sat 25 Nov | 11-1 v FC Augsburg1 FC Union Berlin 1-1 FC Augsburg | German Bundesliga |
| 17 | Wed 29 Nov | 11-1 v Sporting BragaSporting Braga 1-1 1 FC Union Berlin | UEFA Champions League Group C |
| 18 | Sat 9 Dec | 13-1 v Borussia Mönchengladbach1 FC Union Berlin 3-1 Borussia Mönchengladbach | German Bundesliga |
| 19 | Tue 12 Dec | 12-3 v Real Madrid1 FC Union Berlin 2-3 Real Madrid | UEFA Champions League Group C |
| 20 | Sat 16 Dec | 10-3 v VfL BochumVfL Bochum 3-0 1 FC Union Berlin | German Bundesliga |
| 21 | Wed 20 Dec | 12-0 v 1 FC Köln1 FC Union Berlin 2-0 1 FC Köln | German Bundesliga |
| 22 | Sat 13 Jan | 1 0-0 v SC FreiburgSC Freiburg 0-0 1 FC Union Berlin | German Bundesliga |
| 23 | Wed 24 Jan | 10-1 v Bayern MunichBayern Munich 1-0 1 FC Union Berlin | German Bundesliga |
| 24 | Sun 28 Jan | 11-0 v Darmstadt 981 FC Union Berlin 1-0 Darmstadt 98 | German Bundesliga |
| 25 | Wed 7 Feb | 11-1 v Mainz 05Mainz 05 1-1 1 FC Union Berlin | German Bundesliga |
| 26 | Sat 10 Feb | 11-0 v VfL Wolfsburg1 FC Union Berlin 1-0 VfL Wolfsburg | German Bundesliga |
| 27 | Sat 17 Feb | 11-0 v 1899 Hoffenheim1899 Hoffenheim 0-1 1 FC Union Berlin | German Bundesliga |
| 28 | Sat 24 Feb | 12-2 v 1 FC Heidenheim1 FC Union Berlin 2-2 1 FC Heidenheim | German Bundesliga |
| 29 | Sat 2 Mar | 10-2 v Borussia Dortmund1 FC Union Berlin 0-2 Borussia Dortmund | German Bundesliga |
| 30 | Fri 8 Mar | 10-2 v VfB StuttgartVfB Stuttgart 2-0 1 FC Union Berlin | German Bundesliga |
| 31 | Sat 16 Mar | 12-1 v Werder Bremen1 FC Union Berlin 2-1 Werder Bremen | German Bundesliga |
| 32 | Tue 26 Mar | 222-0 v Faroe IslandsDenmark 2-0 Faroe Islands | International Friendly |
| 33 | Sat 30 Mar | 10-0 v Eintracht FrankfurtEintracht Frankfurt 0-0 1 FC Union Berlin | German Bundesliga |
| 34 | Sat 6 Apr | 10-1 v Bayer 04 Leverkusen1 FC Union Berlin 0-1 Bayer 04 Leverkusen | German Bundesliga |
| 35 | Fri 12 Apr | 10-2 v FC AugsburgFC Augsburg 2-0 1 FC Union Berlin | German Bundesliga |
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