| 1 | Sat 17 Aug 2019 | 5-1 v FC AugsburgBorussia Dortmund 5-1 FC Augsburg | German Bundesliga |
| 2 | Fri 23 Aug 2019 | 3-1 v 1. FC Köln1. FC Köln 1-3 Borussia Dortmund | German Bundesliga |
| 3 | Sat 31 Aug 2019 | 1-3 v 1. FC Union Berlin1. FC Union Berlin 3-1 Borussia Dortmund | German Bundesliga |
| 4 | Sat 14 Sep 2019 | 4-0 v Bayer 04 LeverkusenBorussia Dortmund 4-0 Bayer 04 Leverkusen | German Bundesliga |
| 5 | Tue 17 Sep 2019 | 0-0 v BarcelonaBorussia Dortmund 0-0 Barcelona | UEFA Champions League Group F |
| 6 | Sun 22 Sep 2019 | 2-2 v Eintracht FrankfurtEintracht Frankfurt 2-2 Borussia Dortmund | German Bundesliga |
| 7 | Wed 2 Oct 2019 | 2-0 v Slavia PragueSlavia Prague 0-2 Borussia Dortmund | UEFA Champions League Group F |
| 8 | Sat 5 Oct 2019 | 2-2 v SC FreiburgSC Freiburg 2-2 Borussia Dortmund | German Bundesliga |
| 9 | Sat 19 Oct 2019 | 1-0 v Borussia MönchengladbachBorussia Dortmund 1-0 Borussia Mönchengladbach | German Bundesliga |
| 10 | Wed 23 Oct 2019 | 0-2 v Inter MilanInter Milan 2-0 Borussia Dortmund | UEFA Champions League Group F |
| 11 | Sat 26 Oct 2019 | 0-0 v FC Schalke 04FC Schalke 04 0-0 Borussia Dortmund | German Bundesliga |
| 12 | Sat 2 Nov 2019 | 3-0 v VfL WolfsburgBorussia Dortmund 3-0 VfL Wolfsburg | German Bundesliga |
| 13 | Tue 5 Nov 2019 | 3-2 v Inter MilanBorussia Dortmund 3-2 Inter Milan | UEFA Champions League Group F |
| 14 | Sat 9 Nov 2019 | 0-4 v Bayern MunichBayern Munich 4-0 Borussia Dortmund | German Bundesliga |
| 15 | Fri 22 Nov 2019 | 3-3 v SC Paderborn 07Borussia Dortmund 3-3 SC Paderborn 07 | German Bundesliga |
| 16 | Wed 27 Nov 2019 | 1-3 v BarcelonaBarcelona 3-1 Borussia Dortmund | UEFA Champions League Group F |
| 17 | Sat 30 Nov 2019 | 2-1 v Hertha BerlinHertha Berlin 1-2 Borussia Dortmund | German Bundesliga |
| 18 | Tue 10 Dec 2019 | 2-1 v Slavia PragueBorussia Dortmund 2-1 Slavia Prague | UEFA Champions League Group F |
| 19 | Sat 14 Dec 2019 | 4-0 v Mainz 05Mainz 05 0-4 Borussia Dortmund | German Bundesliga |
| 20 | Tue 17 Dec 2019 | 3-3 v RB LeipzigBorussia Dortmund 3-3 RB Leipzig | German Bundesliga |
| 21 | Fri 20 Dec 2019 | 1-2 v 1899 Hoffenheim1899 Hoffenheim 2-1 Borussia Dortmund | German Bundesliga |
| 22 | Sat 18 Jan 2020 | 5-3 v FC AugsburgFC Augsburg 3-5 Borussia Dortmund | German Bundesliga |
| 23 | Fri 24 Jan 2020 | 5-1 v 1. FC KölnBorussia Dortmund 5-1 1. FC Köln | German Bundesliga |
| 24 | Sat 1 Feb 2020 | 5-0 v 1. FC Union BerlinBorussia Dortmund 5-0 1. FC Union Berlin | German Bundesliga |
| 25 | Fri 14 Feb 2020 | 4-0 v Eintracht FrankfurtBorussia Dortmund 4-0 Eintracht Frankfurt | German Bundesliga |
| 26 | Tue 18 Feb 2020 | 2-1 v Paris St GermainBorussia Dortmund 2-1 Paris St Germain | UEFA Champions League Round of 16 |
| 27 | Sat 22 Feb 2020 | 2-0 v Werder BremenWerder Bremen 0-2 Borussia Dortmund | German Bundesliga |
| 28 | Sat 29 Feb 2020 | 1-0 v SC FreiburgBorussia Dortmund 1-0 SC Freiburg | German Bundesliga |
| 29 | Sat 7 Mar 2020 | 2-1 v Borussia MönchengladbachBorussia Mönchengladbach 1-2 Borussia Dortmund | German Bundesliga |
| 30 | Wed 11 Mar 2020 | 0-2 v Paris St GermainParis St Germain 2-0 Borussia Dortmund | UEFA Champions League Round of 16 |
| 31 | Sat 27 Jun 2020 | 150-4 v 1899 HoffenheimBorussia Dortmund 0-4 1899 Hoffenheim | German Bundesliga |
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