| 1 | 10/1/2021 | 142-2 v AjaxAjax 2-2 PSV Eindhoven | Dutch Eredivisie |
| 2 | 13/1/2021 | 141-3 v AZ AlkmaarPSV Eindhoven 1-3 AZ Alkmaar | Dutch Eredivisie |
| 3 | 23/1/2021 | 142-0 v RKC WaalwijkPSV Eindhoven 2-0 RKC Waalwijk | Dutch Eredivisie |
| 4 | 31/1/2021 | 141-3 v FeyenoordFeyenoord 3-1 PSV Eindhoven | Dutch Eredivisie |
| 5 | 6/2/2021 | 143-0 v FC TwentePSV Eindhoven 3-0 FC Twente | Dutch Eredivisie |
| 6 | 13/2/2021 | 142-2 v ADO Den HaagADO Den Haag 2-2 PSV Eindhoven | Dutch Eredivisie |
| 7 | 18/2/2021 | 142-4 v OlympiakosOlympiakos 4-2 PSV Eindhoven | Europa League Round of 32 |
| 8 | 21/2/2021 | 143-1 v VitessePSV Eindhoven 3-1 Vitesse | Dutch Eredivisie |
| 9 | 25/2/2021 | 142-1 v OlympiakosPSV Eindhoven 2-1 Olympiakos | Europa League Round of 32 |
| 10 | 28/2/2021 | 141-1 v AjaxPSV Eindhoven 1-1 Ajax | Dutch Eredivisie |
| 11 | 7/3/2021 | 143-1 v Fortuna SittardFortuna Sittard 1-3 PSV Eindhoven | Dutch Eredivisie |
| 12 | 14/3/2021 | 141-1 v FeyenoordPSV Eindhoven 1-1 Feyenoord | Dutch Eredivisie |
| 13 | 21/3/2021 | 140-2 v AZ AlkmaarAZ Alkmaar 2-0 PSV Eindhoven | Dutch Eredivisie |
| 14 | 4/4/2021 | 143-0 v Heracles AlmeloPSV Eindhoven 3-0 Heracles Almelo | Dutch Eredivisie |
| 15 | 11/4/2021 | 142-0 v VVV VenloVVV Venlo 0-2 PSV Eindhoven | Dutch Eredivisie |
| 16 | 24/4/2021 | 141-0 v FC GroningenPSV Eindhoven 1-0 FC Groningen | Dutch Eredivisie |
| 17 | 2/5/2021 | 142-2 v sc HeerenveenPSV Eindhoven 2-2 sc Heerenveen | Dutch Eredivisie |
| 18 | 9/5/2021 | 142-0 v Willem IIWillem II 0-2 PSV Eindhoven | Dutch Eredivisie |
| 19 | 13/5/2021 | 144-2 v PEC ZwollePSV Eindhoven 4-2 PEC Zwolle | Dutch Eredivisie |
| 20 | 16/5/2021 | 141-1 v FC UtrechtFC Utrecht 1-1 PSV Eindhoven | Dutch Eredivisie |
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