| 1 | Tue 21 Sep 2021 | 2 2-1 v Athletic BilbaoAthletic Bilbao 1-2 Rayo Vallecano | Spanish La Liga |
| 2 | Sun 26 Sep 2021 | 23-1 v CádizRayo Vallecano 3-1 Cádiz | Spanish La Liga |
| 3 | Sun 17 Oct 2021 | 22-1 v ElcheRayo Vallecano 2-1 Elche | Spanish La Liga |
| 4 | Sun 24 Oct 2021 | 22-3 v Real BetisReal Betis 3-2 Rayo Vallecano | Spanish La Liga |
| 5 | Mon 1 Nov 2021 | 20-0 v Celta VigoRayo Vallecano 0-0 Celta Vigo | Spanish La Liga |
| 6 | Sun 2 Jan 2022 | 20-2 v Atlético MadridAtlético Madrid 2-0 Rayo Vallecano | Spanish La Liga |
| 7 | Sun 6 Mar 2022 | 2 0-2 v CádizCádiz 2-0 Rayo Vallecano | Spanish La Liga |
| 8 | Sun 3 Apr 2022 | 22-2 v GranadaGranada 2-2 Rayo Vallecano | Spanish La Liga |
| 9 | Mon 11 Apr 2022 | 21-1 v ValenciaRayo Vallecano 1-1 Valencia | Spanish La Liga |
| 10 | Sat 16 Apr 2022 | 2 0-1 v AlavésAlavés 1-0 Rayo Vallecano | Spanish La Liga |
| 11 | Thu 21 Apr 2022 | 21-0 v EspanyolEspanyol 0-1 Rayo Vallecano | Spanish La Liga |
| 12 | Sun 24 Apr 2022 | 21-0 v BarcelonaBarcelona 0-1 Rayo Vallecano | Spanish La Liga |
| 13 | Sun 1 May 2022 | 21-1 v Real SociedadRayo Vallecano 1-1 Real Sociedad | Spanish La Liga |
| 14 | Sun 8 May 2022 | 20-0 v GetafeGetafe 0-0 Rayo Vallecano | Spanish La Liga |
| 15 | Thu 12 May 2022 | 2 1-5 v VillarrealRayo Vallecano 1-5 Villarreal | Spanish La Liga |
| 16 | Sun 15 May 2022 | 21-2 v MallorcaMallorca 2-1 Rayo Vallecano | Spanish La Liga |
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