| 1 | Sun 18 Aug 2019 | 2-1 v Real BetisReal Betis 1-2 Real Valladolid | Spanish La Liga |
| 2 | Sun 15 Sep 2019 | 1-1 v OsasunaReal Valladolid 1-1 Osasuna | Spanish La Liga |
| 3 | Sat 21 Sep 2019 | 0-2 v VillarrealVillarreal 2-0 Real Valladolid | Spanish La Liga |
| 4 | Tue 24 Sep 2019 | 1-1 v GranadaReal Valladolid 1-1 Granada | Spanish La Liga |
| 5 | Sun 29 Sep 2019 | 2-0 v EspanyolEspanyol 0-2 Real Valladolid | Spanish La Liga |
| 6 | Sun 6 Oct 2019 | 0-0 v Atlético MadridReal Valladolid 0-0 Atlético Madrid | Spanish La Liga |
| 7 | Sun 3 Nov 2019 | 3-0 v MallorcaReal Valladolid 3-0 Mallorca | Spanish La Liga |
| 8 | Sat 9 Nov 2019 | 0-3 v AlavésAlavés 3-0 Real Valladolid | Spanish La Liga |
| 9 | Sun 24 Nov 2019 | 0-1 v SevillaReal Valladolid 0-1 Sevilla | Spanish La Liga |
| 10 | Fri 29 Nov 2019 | 0-0 v Celta VigoCelta Vigo 0-0 Real Valladolid | Spanish La Liga |
| 11 | Sun 8 Dec 2019 | 0-0 v Real SociedadReal Valladolid 0-0 Real Sociedad | Spanish La Liga |
| 12 | Sun 15 Dec 2019 | 0-2 v GetafeGetafe 2-0 Real Valladolid | Spanish La Liga |
| 13 | Sat 21 Dec 2019 | 1-1 v ValenciaReal Valladolid 1-1 Valencia | Spanish La Liga |
| 14 | Fri 3 Jan 2020 | 2-2 v LeganésReal Valladolid 2-2 Leganés | Spanish La Liga |
| 15 | Sat 8 Feb 2020 | 1-1 v VillarrealReal Valladolid 1-1 Villarreal | Spanish La Liga |
| 16 | Sun 23 Feb 2020 | 2-1 v EspanyolReal Valladolid 2-1 Espanyol | Spanish La Liga |
| 17 | Fri 28 Feb 2020 | 0-1 v Real SociedadReal Sociedad 1-0 Real Valladolid | Spanish La Liga |
| 18 | Sun 8 Mar 2020 | 1-4 v Athletic BilbaoReal Valladolid 1-4 Athletic Bilbao | Spanish La Liga |
| 19 | Sat 11 Jul 2020 | 200-1 v BarcelonaReal Valladolid 0-1 Barcelona | Spanish La Liga |
| 20 | Thu 16 Jul 2020 | 201-3 v EibarEibar 3-1 Real Valladolid | Spanish La Liga |
| 21 | Sun 19 Jul 2020 | 202-0 v Real BetisReal Valladolid 2-0 Real Betis | Spanish La Liga |
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