| 1 | Fri 23 Aug 2019 | 141-2 v LevanteLevante 2-1 Villarreal | Spanish La Liga |
| 2 | Fri 27 Sep 2019 | 145-1 v Real BetisVillarreal 5-1 Real Betis | Spanish La Liga |
| 3 | Sat 5 Oct 2019 | 141-2 v OsasunaOsasuna 2-1 Villarreal | Spanish La Liga |
| 4 | Fri 25 Oct 2019 | 144-1 v AlavésVillarreal 4-1 Alavés | Spanish La Liga |
| 5 | Thu 31 Oct 2019 | 141-2 v EibarEibar 2-1 Villarreal | Spanish La Liga |
| 6 | Sun 10 Nov 2019 | 141-3 v MallorcaMallorca 3-1 Villarreal | Spanish La Liga |
| 7 | Sat 30 Nov 2019 | 141-2 v ValenciaValencia 2-1 Villarreal | Spanish La Liga |
| 8 | Fri 6 Dec 2019 | 14 0-0 v Atlético MadridVillarreal 0-0 Atlético Madrid | Spanish La Liga |
| 9 | Sun 15 Dec 2019 | 142-1 v SevillaSevilla 1-2 Villarreal | Spanish La Liga |
| 10 | Sat 21 Dec 2019 | 14 1-0 v GetafeVillarreal 1-0 Getafe | Spanish La Liga |
| 11 | Sun 5 Jan 2020 | 142-1 v Real SociedadReal Sociedad 1-2 Villarreal | Spanish La Liga |
| 12 | Sun 19 Jan 2020 | 14 1-2 v EspanyolVillarreal 1-2 Espanyol | Spanish La Liga |
| 13 | Sat 25 Jan 2020 | 142-1 v AlavésAlavés 1-2 Villarreal | Spanish La Liga |
| 14 | Sat 8 Feb 2020 | 141-1 v Real ValladolidReal Valladolid 1-1 Villarreal | Spanish La Liga |
| 15 | Sat 15 Feb 2020 | 14 2-1 v LevanteVillarreal 2-1 Levante | Spanish La Liga |
| 16 | Sun 23 Feb 2020 | 141-3 v Atlético MadridAtlético Madrid 3-1 Villarreal | Spanish La Liga |
| 17 | Sun 1 Mar 2020 | 140-1 v Athletic BilbaoAthletic Bilbao 1-0 Villarreal | Spanish La Liga |
| 18 | Sun 8 Mar 2020 | 141-2 v LeganésVillarreal 1-2 Leganés | Spanish La Liga |
| 19 | Wed 1 Jul 2020 | 142-0 v Real BetisReal Betis 0-2 Villarreal | Spanish La Liga |
| 20 | Sun 5 Jul 2020 | 141-4 v BarcelonaVillarreal 1-4 Barcelona | Spanish La Liga |
| 21 | Wed 8 Jul 2020 | 143-1 v GetafeGetafe 1-3 Villarreal | Spanish La Liga |
| 22 | Mon 13 Jul 2020 | 14 1-2 v Real SociedadVillarreal 1-2 Real Sociedad | Spanish La Liga |
| 23 | Thu 16 Jul 2020 | 141-2 v Real MadridReal Madrid 2-1 Villarreal | Spanish La Liga |
| 24 | Sun 19 Jul 2020 | 144-0 v EibarVillarreal 4-0 Eibar | Spanish La Liga |
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