| 1 | Thu 22 Oct 2020 | 325-3 v SivassporVillarreal 5-3 Sivasspor | Europa League Group I |
| 2 | Thu 29 Oct 2020 | 323-1 v FK QarabağFK Qarabağ 1-3 Villarreal | Europa League Group I |
| 3 | Thu 5 Nov 2020 | 324-0 v Maccabi Tel-AvivVillarreal 4-0 Maccabi Tel-Aviv | Europa League Group I |
| 4 | Thu 26 Nov 2020 | 321-1 v Maccabi Tel-AvivMaccabi Tel-Aviv 1-1 Villarreal | Europa League Group I |
| 5 | Thu 3 Dec 2020 | 321-0 v SivassporSivasspor 0-1 Villarreal | Europa League Group I |
| 6 | Sun 6 Dec 2020 | 320-0 v ElcheVillarreal 0-0 Elche | Spanish La Liga |
| 7 | Sun 14 Feb 2021 | 321-2 v Real BetisVillarreal 1-2 Real Betis | Spanish La Liga |
| 8 | Thu 25 Feb 2021 | 322-1 v SV Red Bull SalzburgVillarreal 2-1 SV Red Bull Salzburg | Europa League Round of 32 |
| 9 | Sun 28 Feb 2021 | 320-2 v Atlético MadridVillarreal 0-2 Atlético Madrid | Spanish La Liga |
| 10 | Thu 11 Mar 2021 | 322-0 v Dynamo KievDynamo Kiev 0-2 Villarreal | Europa League Round of 16 |
| 11 | Thu 18 Mar 2021 | 322-0 v Dynamo KievVillarreal 2-0 Dynamo Kiev | Europa League Round of 16 |
| 12 | Thu 15 Apr 2021 | 322-1 v Dinamo ZagrebVillarreal 2-1 Dinamo Zagreb | Europa League Quarter Final |
| 13 | Sun 2 May 2021 | 321-0 v GetafeVillarreal 1-0 Getafe | Spanish La Liga |
| 14 | Thu 13 May 2021 | 322-0 v Real ValladolidReal Valladolid 0-2 Villarreal | Spanish La Liga |
| 15 | Sun 16 May 2021 | 324-0 v SevillaVillarreal 4-0 Sevilla | Spanish La Liga |
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