| 1 | Sat 19 Sep 2020 | 242-1 v EibarVillarreal 2-1 Eibar | Spanish La Liga |
| 2 | Sun 18 Oct 2020 | 24 2-1 v ValenciaVillarreal 2-1 Valencia | Spanish La Liga |
| 3 | Thu 22 Oct 2020 | 24 5-3 v SivassporVillarreal 5-3 Sivasspor | Europa League Group I |
| 4 | Sun 25 Oct 2020 | 24 0-0 v CádizCádiz 0-0 Villarreal | Spanish La Liga |
| 5 | Thu 29 Oct 2020 | 243-1 v FK QarabağFK Qarabağ 1-3 Villarreal | Europa League Group I |
| 6 | Mon 2 Nov 2020 | 242-0 v Real ValladolidVillarreal 2-0 Real Valladolid | Spanish La Liga |
| 7 | Sun 8 Nov 2020 | 24 3-1 v GetafeGetafe 1-3 Villarreal | Spanish La Liga |
| 8 | Sat 21 Nov 2020 | 241-1 v Real MadridVillarreal 1-1 Real Madrid | Spanish La Liga |
| 9 | Thu 26 Nov 2020 | 241-1 v Maccabi Tel-AvivMaccabi Tel-Aviv 1-1 Villarreal | Europa League Group I |
| 10 | Sun 29 Nov 2020 | 241-1 v Real SociedadReal Sociedad 1-1 Villarreal | Spanish La Liga |
| 11 | Sun 13 Dec 2020 | 24 1-1 v Real BetisReal Betis 1-1 Villarreal | Spanish La Liga |
| 12 | Tue 22 Dec 2020 | 241-1 v Athletic BilbaoVillarreal 1-1 Athletic Bilbao | Spanish La Liga |
| 13 | Tue 29 Dec 2020 | 240-2 v SevillaSevilla 2-0 Villarreal | Spanish La Liga |
| 14 | Sat 2 Jan 2021 | 242-1 v LevanteVillarreal 2-1 Levante | Spanish La Liga |
| 15 | Fri 8 Jan 2021 | 244-0 v Celta VigoCelta Vigo 0-4 Villarreal | Spanish La Liga |
| 16 | Wed 20 Jan 2021 | 242-2 v GranadaVillarreal 2-2 Granada | Spanish La Liga |
| 17 | Sat 23 Jan 2021 | 240-0 v HuescaHuesca 0-0 Villarreal | Spanish La Liga |
| 18 | Sat 30 Jan 2021 | 241-1 v Real SociedadVillarreal 1-1 Real Sociedad | Spanish La Liga |
| 19 | Sat 6 Feb 2021 | 24 2-2 v ElcheElche 2-2 Villarreal | Spanish La Liga |
| 20 | Sun 14 Feb 2021 | 241-2 v Real BetisVillarreal 1-2 Real Betis | Spanish La Liga |
| 21 | Thu 18 Feb 2021 | 242-0 v SV Red Bull SalzburgSV Red Bull Salzburg 0-2 Villarreal | Europa League Round of 32 |
| 22 | Sun 21 Feb 2021 | 241-1 v Athletic BilbaoAthletic Bilbao 1-1 Villarreal | Spanish La Liga |
| 23 | Thu 25 Feb 2021 | 242-1 v SV Red Bull SalzburgVillarreal 2-1 SV Red Bull Salzburg | Europa League Round of 32 |
| 24 | Sun 28 Feb 2021 | 240-2 v Atlético MadridVillarreal 0-2 Atlético Madrid | Spanish La Liga |
| 25 | Fri 5 Mar 2021 | 241-2 v ValenciaValencia 2-1 Villarreal | Spanish La Liga |
| 26 | Thu 11 Mar 2021 | 24 2-0 v Dynamo KievDynamo Kiev 0-2 Villarreal | Europa League Round of 16 |
| 27 | Sun 14 Mar 2021 | 24 3-1 v EibarEibar 1-3 Villarreal | Spanish La Liga |
| 28 | Thu 18 Mar 2021 | 242-0 v Dynamo KievVillarreal 2-0 Dynamo Kiev | Europa League Round of 16 |
| 29 | Sun 21 Mar 2021 | 242-1 v CádizVillarreal 2-1 Cádiz | Spanish La Liga |
| 30 | Sat 3 Apr 2021 | 243-0 v GranadaGranada 0-3 Villarreal | Spanish La Liga |
| 31 | Thu 8 Apr 2021 | 241-0 v Dinamo ZagrebDinamo Zagreb 0-1 Villarreal | Europa League Quarter Final |
| 32 | Sun 11 Apr 2021 | 241-2 v OsasunaVillarreal 1-2 Osasuna | Spanish La Liga |
| 33 | Thu 15 Apr 2021 | 242-1 v Dinamo ZagrebVillarreal 2-1 Dinamo Zagreb | Europa League Quarter Final |
| 34 | Sun 18 Apr 2021 | 245-1 v LevanteLevante 1-5 Villarreal | Spanish La Liga |
| 35 | Wed 21 Apr 2021 | 24 1-2 v AlavésAlavés 2-1 Villarreal | Spanish La Liga |
| 36 | Thu 29 Apr 2021 | 242-1 v ArsenalVillarreal 2-1 Arsenal | Europa League Semi Final |
| 37 | Thu 6 May 2021 | 240-0 v ArsenalArsenal 0-0 Villarreal | Europa League Semi Final |
| 38 | Thu 13 May 2021 | 242-0 v Real ValladolidReal Valladolid 0-2 Villarreal | Spanish La Liga |
| 39 | Sat 22 May 2021 | 241-2 v Real MadridReal Madrid 2-1 Villarreal | Spanish La Liga |
| 40 | Wed 26 May 2021 | 241-1 v Manchester UnitedVillarreal 1-1 Manchester United | Europa League Final |
| 41 | Wed 11 Aug 2021 | 241-1 v ChelseaChelsea 1-1 Villarreal | UEFA Super Cup Final |
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