| 1 | Fri 8 Jan 2021 | 254-0 v Celta VigoCelta Vigo 0-4 Villarreal | Spanish La Liga |
| 2 | Wed 20 Jan 2021 | 252-2 v GranadaVillarreal 2-2 Granada | Spanish La Liga |
| 3 | Sat 23 Jan 2021 | 25 0-0 v HuescaHuesca 0-0 Villarreal | Spanish La Liga |
| 4 | Sat 30 Jan 2021 | 25 1-1 v Real SociedadVillarreal 1-1 Real Sociedad | Spanish La Liga |
| 5 | Thu 18 Feb 2021 | 252-0 v SV Red Bull SalzburgSV Red Bull Salzburg 0-2 Villarreal | Europa League Round of 32 |
| 6 | Sun 21 Feb 2021 | 25 1-1 v Athletic BilbaoAthletic Bilbao 1-1 Villarreal | Spanish La Liga |
| 7 | Thu 25 Feb 2021 | 252-1 v SV Red Bull SalzburgVillarreal 2-1 SV Red Bull Salzburg | Europa League Round of 32 |
| 8 | Sun 28 Feb 2021 | 250-2 v Atlético MadridVillarreal 0-2 Atlético Madrid | Spanish La Liga |
| 9 | Fri 5 Mar 2021 | 25 1-2 v ValenciaValencia 2-1 Villarreal | Spanish La Liga |
| 10 | Thu 11 Mar 2021 | 25 2-0 v Dynamo KievDynamo Kiev 0-2 Villarreal | Europa League Round of 16 |
| 11 | Sun 14 Mar 2021 | 25 3-1 v EibarEibar 1-3 Villarreal | Spanish La Liga |
| 12 | Thu 18 Mar 2021 | 252-0 v Dynamo KievVillarreal 2-0 Dynamo Kiev | Europa League Round of 16 |
| 13 | Sat 3 Apr 2021 | 253-0 v GranadaGranada 0-3 Villarreal | Spanish La Liga |
| 14 | Thu 8 Apr 2021 | 251-0 v Dinamo ZagrebDinamo Zagreb 0-1 Villarreal | Europa League Quarter Final |
| 15 | Thu 15 Apr 2021 | 25 2-1 v Dinamo ZagrebVillarreal 2-1 Dinamo Zagreb | Europa League Quarter Final |
| 16 | Sun 18 Apr 2021 | 255-1 v LevanteLevante 1-5 Villarreal | Spanish La Liga |
| 17 | Wed 21 Apr 2021 | 251-2 v AlavésAlavés 2-1 Villarreal | Spanish La Liga |
| 18 | Sun 25 Apr 2021 | 251-2 v BarcelonaVillarreal 1-2 Barcelona | Spanish La Liga |
| 19 | Thu 29 Apr 2021 | 25 2-1 v ArsenalVillarreal 2-1 Arsenal | Europa League Semi Final |
| 20 | Sun 2 May 2021 | 251-0 v GetafeVillarreal 1-0 Getafe | Spanish La Liga |
| 21 | Sun 9 May 2021 | 252-4 v Celta VigoVillarreal 2-4 Celta Vigo | Spanish La Liga |
| 22 | Thu 13 May 2021 | 25 2-0 v Real ValladolidReal Valladolid 0-2 Villarreal | Spanish La Liga |
| 23 | Sat 22 May 2021 | 251-2 v Real MadridReal Madrid 2-1 Villarreal | Spanish La Liga |
| 24 | Wed 26 May 2021 | 25 1-1 v Manchester UnitedVillarreal 1-1 Manchester United | Europa League Final |
| 25 | Wed 11 Aug 2021 | 251-1 v ChelseaChelsea 1-1 Villarreal | UEFA Super Cup Final |
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