| 1 | Sun 25 Oct 2020 | 300-0 v CádizCádiz 0-0 Villarreal | Spanish La Liga |
| 2 | Thu 29 Oct 2020 | 303-1 v FK QarabağFK Qarabağ 1-3 Villarreal | Europa League Group I |
| 3 | Mon 2 Nov 2020 | 302-0 v Real ValladolidVillarreal 2-0 Real Valladolid | Spanish La Liga |
| 4 | Thu 5 Nov 2020 | 304-0 v Maccabi Tel-AvivVillarreal 4-0 Maccabi Tel-Aviv | Europa League Group I |
| 5 | Sat 21 Nov 2020 | 30 1-1 v Real MadridVillarreal 1-1 Real Madrid | Spanish La Liga |
| 6 | Thu 26 Nov 2020 | 301-1 v Maccabi Tel-AvivMaccabi Tel-Aviv 1-1 Villarreal | Europa League Group I |
| 7 | Thu 3 Dec 2020 | 301-0 v SivassporSivasspor 0-1 Villarreal | Europa League Group I |
| 8 | Sun 6 Dec 2020 | 300-0 v ElcheVillarreal 0-0 Elche | Spanish La Liga |
| 9 | Sun 13 Dec 2020 | 301-1 v Real BetisReal Betis 1-1 Villarreal | Spanish La Liga |
| 10 | Sat 19 Dec 2020 | 30 3-1 v OsasunaOsasuna 1-3 Villarreal | Spanish La Liga |
| 11 | Tue 22 Dec 2020 | 301-1 v Athletic BilbaoVillarreal 1-1 Athletic Bilbao | Spanish La Liga |
| 12 | Tue 29 Dec 2020 | 300-2 v SevillaSevilla 2-0 Villarreal | Spanish La Liga |
| 13 | Sat 2 Jan 2021 | 30 2-1 v LevanteVillarreal 2-1 Levante | Spanish La Liga |
| 14 | Fri 8 Jan 2021 | 304-0 v Celta VigoCelta Vigo 0-4 Villarreal | Spanish La Liga |
| 15 | Wed 20 Jan 2021 | 302-2 v GranadaVillarreal 2-2 Granada | Spanish La Liga |
| 16 | Sat 23 Jan 2021 | 300-0 v HuescaHuesca 0-0 Villarreal | Spanish La Liga |
| 17 | Sat 6 Feb 2021 | 302-2 v ElcheElche 2-2 Villarreal | Spanish La Liga |
| 18 | Thu 18 Feb 2021 | 302-0 v SV Red Bull SalzburgSV Red Bull Salzburg 0-2 Villarreal | Europa League Round of 32 |
| 19 | Sun 21 Feb 2021 | 301-1 v Athletic BilbaoAthletic Bilbao 1-1 Villarreal | Spanish La Liga |
| 20 | Thu 18 Mar 2021 | 302-0 v Dynamo KievVillarreal 2-0 Dynamo Kiev | Europa League Round of 16 |
| 21 | Sun 21 Mar 2021 | 302-1 v CádizVillarreal 2-1 Cádiz | Spanish La Liga |
| 22 | Sun 11 Apr 2021 | 301-2 v OsasunaVillarreal 1-2 Osasuna | Spanish La Liga |
| 23 | Sun 18 Apr 2021 | 305-1 v LevanteLevante 1-5 Villarreal | Spanish La Liga |
| 24 | Wed 21 Apr 2021 | 301-2 v AlavésAlavés 2-1 Villarreal | Spanish La Liga |
| 25 | Sun 25 Apr 2021 | 301-2 v BarcelonaVillarreal 1-2 Barcelona | Spanish La Liga |
| 26 | Sun 2 May 2021 | 301-0 v GetafeVillarreal 1-0 Getafe | Spanish La Liga |
| 27 | Thu 6 May 2021 | 30 0-0 v ArsenalArsenal 0-0 Villarreal | Europa League Semi Final |
| 28 | Sun 9 May 2021 | 30 2-4 v Celta VigoVillarreal 2-4 Celta Vigo | Spanish La Liga |
| 29 | Thu 13 May 2021 | 302-0 v Real ValladolidReal Valladolid 0-2 Villarreal | Spanish La Liga |
| 30 | Sun 16 May 2021 | 304-0 v SevillaVillarreal 4-0 Sevilla | Spanish La Liga |
| 31 | Sat 22 May 2021 | 301-2 v Real MadridReal Madrid 2-1 Villarreal | Spanish La Liga |
| 32 | Wed 26 May 2021 | 301-1 v Manchester UnitedVillarreal 1-1 Manchester United | Europa League Final |
| 33 | Wed 11 Aug 2021 | 21 1-1 v ChelseaChelsea 1-1 Villarreal | UEFA Super Cup Final |
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