| 1 | Mon 16 Aug 2021 | 180-0 v GranadaVillarreal 0-0 Granada | Spanish La Liga |
| 2 | Sat 21 Aug 2021 | 18 0-0 v EspanyolEspanyol 0-0 Villarreal | Spanish La Liga |
| 3 | Sun 29 Aug 2021 | 182-2 v Atlético MadridAtlético Madrid 2-2 Villarreal | Spanish La Liga |
| 4 | Tue 14 Sep 2021 | 182-2 v AtalantaVillarreal 2-2 Atalanta | UEFA Champions League Group F |
| 5 | Sun 19 Sep 2021 | 180-0 v MallorcaMallorca 0-0 Villarreal | Spanish La Liga |
| 6 | Wed 22 Sep 2021 | 184-1 v ElcheVillarreal 4-1 Elche | Spanish La Liga |
| 7 | Sat 25 Sep 2021 | 180-0 v Real MadridReal Madrid 0-0 Villarreal | Spanish La Liga |
| 8 | Wed 29 Sep 2021 | 18 1-2 v Manchester UnitedManchester United 2-1 Villarreal | UEFA Champions League Group F |
| 9 | Sun 3 Oct 2021 | 182-0 v Real BetisVillarreal 2-0 Real Betis | Spanish La Liga |
| 10 | Sun 17 Oct 2021 | 181-2 v OsasunaVillarreal 1-2 Osasuna | Spanish La Liga |
| 11 | Wed 20 Oct 2021 | 184-1 v Young BoysYoung Boys 1-4 Villarreal | UEFA Champions League Group F |
| 12 | Sat 23 Oct 2021 | 18 1-2 v Athletic BilbaoAthletic Bilbao 2-1 Villarreal | Spanish La Liga |
| 13 | Sat 30 Oct 2021 | 180-2 v ValenciaValencia 2-0 Villarreal | Spanish La Liga |
| 14 | Tue 2 Nov 2021 | 182-0 v Young BoysVillarreal 2-0 Young Boys | UEFA Champions League Group F |
| 15 | Sun 7 Nov 2021 | 181-0 v GetafeVillarreal 1-0 Getafe | Spanish La Liga |
| 16 | Sat 20 Nov 2021 | 181-1 v Celta VigoCelta Vigo 1-1 Villarreal | Spanish La Liga |
| 17 | Tue 23 Nov 2021 | 180-2 v Manchester UnitedVillarreal 0-2 Manchester United | UEFA Champions League Group F |
| 18 | Sat 4 Dec 2021 | 180-1 v SevillaSevilla 1-0 Villarreal | Spanish La Liga |
| 19 | Thu 9 Dec 2021 | 18 3-2 v AtalantaAtalanta 2-3 Villarreal | UEFA Champions League Group F |
| 20 | Sun 12 Dec 2021 | 182-0 v Rayo VallecanoVillarreal 2-0 Rayo Vallecano | Spanish La Liga |
| 21 | Sat 18 Dec 2021 | 183-1 v Real SociedadReal Sociedad 1-3 Villarreal | Spanish La Liga |
| 22 | Tue 21 Dec 2021 | 185-2 v AlavésVillarreal 5-2 Alavés | Spanish La Liga |
| 23 | Mon 3 Jan 2022 | 185-0 v LevanteVillarreal 5-0 Levante | Spanish La Liga |
| 24 | Sun 9 Jan 2022 | 182-2 v Atlético MadridVillarreal 2-2 Atlético Madrid | Spanish La Liga |
| 25 | Sun 16 Jan 2022 | 180-1 v ElcheElche 1-0 Villarreal | Spanish La Liga |
| 26 | Sat 22 Jan 2022 | 183-0 v MallorcaVillarreal 3-0 Mallorca | Spanish La Liga |
| 27 | Sun 6 Feb 2022 | 18 2-0 v Real BetisReal Betis 0-2 Villarreal | Spanish La Liga |
| 28 | Sat 12 Feb 2022 | 180-0 v Real MadridVillarreal 0-0 Real Madrid | Spanish La Liga |
| 29 | Sat 19 Feb 2022 | 184-1 v GranadaGranada 1-4 Villarreal | Spanish La Liga |
| 30 | Tue 22 Feb 2022 | 181-1 v JuventusVillarreal 1-1 Juventus | UEFA Champions League Round of 16 |
| 31 | Sat 5 Mar 2022 | 180-1 v OsasunaOsasuna 1-0 Villarreal | Spanish La Liga |
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