| 1 | Mon 16 Aug 2021 | 7 0-0 v GranadaVillarreal 0-0 Granada | Spanish La Liga |
| 2 | Sat 21 Aug 2021 | 70-0 v EspanyolEspanyol 0-0 Villarreal | Spanish La Liga |
| 3 | Sun 29 Aug 2021 | 7 2-2 v Atlético MadridAtlético Madrid 2-2 Villarreal | Spanish La Liga |
| 4 | Tue 14 Sep 2021 | 7 2-2 v AtalantaVillarreal 2-2 Atalanta | UEFA Champions League Group F |
| 5 | Sun 17 Oct 2021 | 71-2 v OsasunaVillarreal 1-2 Osasuna | Spanish La Liga |
| 6 | Wed 20 Oct 2021 | 74-1 v Young BoysYoung Boys 1-4 Villarreal | UEFA Champions League Group F |
| 7 | Sat 23 Oct 2021 | 71-2 v Athletic BilbaoAthletic Bilbao 2-1 Villarreal | Spanish La Liga |
| 8 | Sat 4 Dec 2021 | 70-1 v SevillaSevilla 1-0 Villarreal | Spanish La Liga |
| 9 | Thu 9 Dec 2021 | 73-2 v AtalantaAtalanta 2-3 Villarreal | UEFA Champions League Group F |
| 10 | Sun 12 Dec 2021 | 72-0 v Rayo VallecanoVillarreal 2-0 Rayo Vallecano | Spanish La Liga |
| 11 | Sat 18 Dec 2021 | 73-1 v Real SociedadReal Sociedad 1-3 Villarreal | Spanish La Liga |
| 12 | Tue 21 Dec 2021 | 75-2 v AlavésVillarreal 5-2 Alavés | Spanish La Liga |
| 13 | Mon 3 Jan 2022 | 75-0 v LevanteVillarreal 5-0 Levante | Spanish La Liga |
| 14 | Sun 9 Jan 2022 | 72-2 v Atlético MadridVillarreal 2-2 Atlético Madrid | Spanish La Liga |
| 15 | Sun 16 Jan 2022 | 70-1 v ElcheElche 1-0 Villarreal | Spanish La Liga |
| 16 | Sun 6 Feb 2022 | 72-0 v Real BetisReal Betis 0-2 Villarreal | Spanish La Liga |
| 17 | Wed 16 Mar 2022 | 73-0 v JuventusJuventus 0-3 Villarreal | UEFA Champions League Round of 16 |
| 18 | Sun 20 Mar 2022 | 70-1 v CádizCádiz 1-0 Villarreal | Spanish La Liga |
| 19 | Sat 2 Apr 2022 | 70-2 v LevanteLevante 2-0 Villarreal | Spanish La Liga |
| 20 | Wed 6 Apr 2022 | 71-0 v Bayern MunichVillarreal 1-0 Bayern Munich | UEFA Champions League Quarter Final |
| 21 | Sat 9 Apr 2022 | 71-1 v Athletic BilbaoVillarreal 1-1 Athletic Bilbao | Spanish La Liga |
| 22 | Tue 12 Apr 2022 | 71-1 v Bayern MunichBayern Munich 1-1 Villarreal | UEFA Champions League Quarter Final |
| 23 | Sat 16 Apr 2022 | 72-1 v GetafeGetafe 1-2 Villarreal | Spanish La Liga |
| 24 | Tue 3 May 2022 | 72-3 v LiverpoolVillarreal 2-3 Liverpool | UEFA Champions League Semi Final |
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