| 1 | 16/8/2021 | 230-0 v GranadaVillarreal 0-0 Granada | Spanish La Liga |
| 2 | 21/8/2021 | 23 0-0 v EspanyolEspanyol 0-0 Villarreal | Spanish La Liga |
| 3 | 14/9/2021 | 232-2 v AtalantaVillarreal 2-2 Atalanta | UEFA Champions League Group F |
| 4 | 19/9/2021 | 230-0 v MallorcaMallorca 0-0 Villarreal | Spanish La Liga |
| 5 | 22/9/2021 | 234-1 v ElcheVillarreal 4-1 Elche | Spanish La Liga |
| 6 | 25/9/2021 | 23 0-0 v Real MadridReal Madrid 0-0 Villarreal | Spanish La Liga |
| 7 | 29/9/2021 | 231-2 v Manchester UnitedManchester United 2-1 Villarreal | UEFA Champions League Group F |
| 8 | 3/10/2021 | 232-0 v Real BetisVillarreal 2-0 Real Betis | Spanish La Liga |
| 9 | 17/10/2021 | 231-2 v OsasunaVillarreal 1-2 Osasuna | Spanish La Liga |
| 10 | 20/10/2021 | 234-1 v Young BoysYoung Boys 1-4 Villarreal | UEFA Champions League Group F |
| 11 | 30/10/2021 | 230-2 v ValenciaValencia 2-0 Villarreal | Spanish La Liga |
| 12 | 2/11/2021 | 232-0 v Young BoysVillarreal 2-0 Young Boys | UEFA Champions League Group F |
| 13 | 7/11/2021 | 231-0 v GetafeVillarreal 1-0 Getafe | Spanish La Liga |
| 14 | 20/11/2021 | 231-1 v Celta VigoCelta Vigo 1-1 Villarreal | Spanish La Liga |
| 15 | 23/11/2021 | 230-2 v Manchester UnitedVillarreal 0-2 Manchester United | UEFA Champions League Group F |
| 16 | 27/11/2021 | 231-3 v BarcelonaVillarreal 1-3 Barcelona | Spanish La Liga |
| 17 | 4/12/2021 | 230-1 v SevillaSevilla 1-0 Villarreal | Spanish La Liga |
| 18 | 9/12/2021 | 233-2 v AtalantaAtalanta 2-3 Villarreal | UEFA Champions League Group F |
| 19 | 12/12/2021 | 232-0 v Rayo VallecanoVillarreal 2-0 Rayo Vallecano | Spanish La Liga |
| 20 | 18/12/2021 | 233-1 v Real SociedadReal Sociedad 1-3 Villarreal | Spanish La Liga |
| 21 | 21/12/2021 | 235-2 v AlavésVillarreal 5-2 Alavés | Spanish La Liga |
| 22 | 3/1/2022 | 235-0 v LevanteVillarreal 5-0 Levante | Spanish La Liga |
| 23 | 9/1/2022 | 232-2 v Atlético MadridVillarreal 2-2 Atlético Madrid | Spanish La Liga |
| 24 | 16/1/2022 | 230-1 v ElcheElche 1-0 Villarreal | Spanish La Liga |
| 25 | 22/1/2022 | 233-0 v MallorcaVillarreal 3-0 Mallorca | Spanish La Liga |
| 26 | 19/2/2022 | 234-1 v GranadaGranada 1-4 Villarreal | Spanish La Liga |
| 27 | 27/2/2022 | 235-1 v EspanyolVillarreal 5-1 Espanyol | Spanish La Liga |
| 28 | 5/3/2022 | 230-1 v OsasunaOsasuna 1-0 Villarreal | Spanish La Liga |
| 29 | 12/3/2022 | 231-0 v Celta VigoVillarreal 1-0 Celta Vigo | Spanish La Liga |
| 30 | 20/3/2022 | 230-1 v CádizCádiz 1-0 Villarreal | Spanish La Liga |
| 31 | 9/4/2022 | 231-1 v Athletic BilbaoVillarreal 1-1 Athletic Bilbao | Spanish La Liga |
| 32 | 16/4/2022 | 232-1 v GetafeGetafe 1-2 Villarreal | Spanish La Liga |
| 33 | 19/4/2022 | 232-0 v ValenciaVillarreal 2-0 Valencia | Spanish La Liga |
| 34 | 30/4/2022 | 231-2 v AlavésAlavés 2-1 Villarreal | Spanish La Liga |
| 35 | 22/5/2022 | 232-0 v BarcelonaBarcelona 0-2 Villarreal | Spanish La Liga |
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