| 1 | Sun 3 Oct 2021 | 102-0 v Real BetisVillarreal 2-0 Real Betis | Spanish La Liga |
| 2 | Tue 26 Oct 2021 | 103-3 v CádizVillarreal 3-3 Cádiz | Spanish La Liga |
| 3 | Sat 20 Nov 2021 | 101-1 v Celta VigoCelta Vigo 1-1 Villarreal | Spanish La Liga |
| 4 | Thu 9 Dec 2021 | 103-2 v AtalantaAtalanta 2-3 Villarreal | UEFA Champions League Group F |
| 5 | Sun 12 Dec 2021 | 102-0 v Rayo VallecanoVillarreal 2-0 Rayo Vallecano | Spanish La Liga |
| 6 | Sat 18 Dec 2021 | 103-1 v Real SociedadReal Sociedad 1-3 Villarreal | Spanish La Liga |
| 7 | Tue 21 Dec 2021 | 105-2 v AlavésVillarreal 5-2 Alavés | Spanish La Liga |
| 8 | Mon 3 Jan 2022 | 10 5-0 v LevanteVillarreal 5-0 Levante | Spanish La Liga |
| 9 | Sun 9 Jan 2022 | 102-2 v Atlético MadridVillarreal 2-2 Atlético Madrid | Spanish La Liga |
| 10 | Sun 16 Jan 2022 | 10 0-1 v ElcheElche 1-0 Villarreal | Spanish La Liga |
| 11 | Sat 22 Jan 2022 | 103-0 v MallorcaVillarreal 3-0 Mallorca | Spanish La Liga |
| 12 | Sat 12 Feb 2022 | 100-0 v Real MadridVillarreal 0-0 Real Madrid | Spanish La Liga |
| 13 | Sat 19 Feb 2022 | 10 4-1 v GranadaGranada 1-4 Villarreal | Spanish La Liga |
| 14 | Sun 27 Feb 2022 | 105-1 v EspanyolVillarreal 5-1 Espanyol | Spanish La Liga |
| 15 | Sat 12 Mar 2022 | 10 1-0 v Celta VigoVillarreal 1-0 Celta Vigo | Spanish La Liga |
| 16 | Sun 20 Mar 2022 | 100-1 v CádizCádiz 1-0 Villarreal | Spanish La Liga |
| 17 | Sat 9 Apr 2022 | 101-1 v Athletic BilbaoVillarreal 1-1 Athletic Bilbao | Spanish La Liga |
| 18 | Sat 16 Apr 2022 | 102-1 v GetafeGetafe 1-2 Villarreal | Spanish La Liga |
| 19 | Tue 19 Apr 2022 | 102-0 v ValenciaVillarreal 2-0 Valencia | Spanish La Liga |
| 20 | Sat 30 Apr 2022 | 101-2 v AlavésAlavés 2-1 Villarreal | Spanish La Liga |
| 21 | Thu 12 May 2022 | 105-1 v Rayo VallecanoRayo Vallecano 1-5 Villarreal | Spanish La Liga |
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