| 1 | Sun 3 Sep | 19 0-3 v RB Leipzig1 FC Union Berlin 0-3 RB Leipzig | German Bundesliga |
| 2 | Sat 16 Sep | 191-2 v VfL WolfsburgVfL Wolfsburg 2-1 1 FC Union Berlin | German Bundesliga |
| 3 | Sat 23 Sep | 190-2 v 1899 Hoffenheim1 FC Union Berlin 0-2 1899 Hoffenheim | German Bundesliga |
| 4 | Tue 3 Oct | 192-3 v Sporting Braga1 FC Union Berlin 2-3 Sporting Braga | UEFA Champions League Group C |
| 5 | Sat 7 Oct | 192-4 v Borussia DortmundBorussia Dortmund 4-2 1 FC Union Berlin | German Bundesliga |
| 6 | Sat 21 Oct | 19 0-3 v VfB Stuttgart1 FC Union Berlin 0-3 VfB Stuttgart | German Bundesliga |
| 7 | Tue 24 Oct | 19 0-1 v Napoli1 FC Union Berlin 0-1 Napoli | UEFA Champions League Group C |
| 8 | Sat 28 Oct | 190-2 v Werder BremenWerder Bremen 2-0 1 FC Union Berlin | German Bundesliga |
| 9 | Sat 4 Nov | 190-3 v Eintracht Frankfurt1 FC Union Berlin 0-3 Eintracht Frankfurt | German Bundesliga |
| 10 | Wed 8 Nov | 191-1 v NapoliNapoli 1-1 1 FC Union Berlin | UEFA Champions League Group C |
| 11 | Sun 12 Nov | 190-4 v Bayer 04 LeverkusenBayer 04 Leverkusen 4-0 1 FC Union Berlin | German Bundesliga |
| 12 | Sat 25 Nov | 19 1-1 v FC Augsburg1 FC Union Berlin 1-1 FC Augsburg | German Bundesliga |
| 13 | Wed 29 Nov | 191-1 v Sporting BragaSporting Braga 1-1 1 FC Union Berlin | UEFA Champions League Group C |
| 14 | Sat 9 Dec | 193-1 v Borussia Mönchengladbach1 FC Union Berlin 3-1 Borussia Mönchengladbach | German Bundesliga |
| 15 | Tue 12 Dec | 192-3 v Real Madrid1 FC Union Berlin 2-3 Real Madrid | UEFA Champions League Group C |
| 16 | Sat 16 Dec | 190-3 v VfL BochumVfL Bochum 3-0 1 FC Union Berlin | German Bundesliga |
| 17 | Wed 20 Dec | 192-0 v 1 FC Köln1 FC Union Berlin 2-0 1 FC Köln | German Bundesliga |
| 18 | Sat 13 Jan | 190-0 v SC FreiburgSC Freiburg 0-0 1 FC Union Berlin | German Bundesliga |
| 19 | Wed 24 Jan | 19 0-1 v Bayern MunichBayern Munich 1-0 1 FC Union Berlin | German Bundesliga |
| 20 | Sun 28 Jan | 191-0 v Darmstadt 981 FC Union Berlin 1-0 Darmstadt 98 | German Bundesliga |
| 21 | Sun 4 Feb | 190-2 v RB LeipzigRB Leipzig 2-0 1 FC Union Berlin | German Bundesliga |
| 22 | Wed 7 Feb | 19 1-1 v Mainz 05Mainz 05 1-1 1 FC Union Berlin | German Bundesliga |
| 23 | Fri 12 Apr | 190-2 v FC AugsburgFC Augsburg 2-0 1 FC Union Berlin | German Bundesliga |
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