| 1 | Sun 15 Aug 2021 | 24-2 v Real SociedadBarcelona 4-2 Real Sociedad | Spanish La Liga |
| 2 | Sat 21 Aug 2021 | 21-1 v Athletic BilbaoAthletic Bilbao 1-1 Barcelona | Spanish La Liga |
| 3 | Sun 29 Aug 2021 | 22-1 v GetafeBarcelona 2-1 Getafe | Spanish La Liga |
| 4 | Mon 20 Sep 2021 | 21-1 v GranadaBarcelona 1-1 Granada | Spanish La Liga |
| 5 | Thu 23 Sep 2021 | 20-0 v CádizCádiz 0-0 Barcelona | Spanish La Liga |
| 6 | Sun 26 Sep 2021 | 23-0 v LevanteBarcelona 3-0 Levante | Spanish La Liga |
| 7 | Wed 29 Sep 2021 | 2 0-3 v BenficaBenfica 3-0 Barcelona | UEFA Champions League Group E |
| 8 | Sat 2 Oct 2021 | 20-2 v Atlético MadridAtlético Madrid 2-0 Barcelona | Spanish La Liga |
| 9 | Sun 17 Oct 2021 | 23-1 v ValenciaBarcelona 3-1 Valencia | Spanish La Liga |
| 10 | Wed 20 Oct 2021 | 21-0 v Dynamo KievBarcelona 1-0 Dynamo Kiev | UEFA Champions League Group E |
| 11 | Sun 24 Oct 2021 | 21-2 v Real MadridBarcelona 1-2 Real Madrid | Spanish La Liga |
| 12 | Wed 27 Oct 2021 | 20-1 v Rayo VallecanoRayo Vallecano 1-0 Barcelona | Spanish La Liga |
| 13 | Sat 30 Oct 2021 | 21-1 v AlavésBarcelona 1-1 Alavés | Spanish La Liga |
| 14 | Tue 23 Nov 2021 | 20-0 v BenficaBarcelona 0-0 Benfica | UEFA Champions League Group E |
| 15 | Sat 4 Dec 2021 | 20-1 v Real BetisBarcelona 0-1 Real Betis | Spanish La Liga |
| 16 | Wed 8 Dec 2021 | 20-3 v Bayern MunichBayern Munich 3-0 Barcelona | UEFA Champions League Group E |
| 17 | Sun 23 Jan 2022 | 21-0 v AlavésAlavés 0-1 Barcelona | Spanish La Liga |
| 18 | Sun 6 Feb 2022 | 24-2 v Atlético MadridBarcelona 4-2 Atlético Madrid | Spanish La Liga |
| 19 | Sun 13 Feb 2022 | 22-2 v EspanyolEspanyol 2-2 Barcelona | Spanish La Liga |
| 20 | Thu 17 Feb 2022 | 21-1 v NapoliBarcelona 1-1 Napoli | UEFA Europa League Round of 32 |
| 21 | Sun 20 Feb 2022 | 2 4-1 v ValenciaValencia 1-4 Barcelona | Spanish La Liga |
| 22 | Thu 24 Feb 2022 | 24-2 v NapoliNapoli 2-4 Barcelona | UEFA Europa League Round of 32 |
| 23 | Sun 27 Feb 2022 | 24-0 v Athletic BilbaoBarcelona 4-0 Athletic Bilbao | Spanish La Liga |
| 24 | Sun 6 Mar 2022 | 22-1 v ElcheElche 1-2 Barcelona | Spanish La Liga |
| 25 | Thu 10 Mar 2022 | 20-0 v GalatasarayBarcelona 0-0 Galatasaray | UEFA Europa League Round of 16 |
| 26 | Thu 17 Mar 2022 | 22-1 v GalatasarayGalatasaray 1-2 Barcelona | UEFA Europa League Round of 16 |
| 27 | Thu 14 Apr 2022 | 22-3 v Eintracht FrankfurtBarcelona 2-3 Eintracht Frankfurt | UEFA Europa League Quarter Final |
| 28 | Mon 18 Apr 2022 | 2 0-1 v CádizBarcelona 0-1 Cádiz | Spanish La Liga |
| 29 | Thu 21 Apr 2022 | 21-0 v Real SociedadReal Sociedad 0-1 Barcelona | Spanish La Liga |
| 30 | Sun 24 Apr 2022 | 20-1 v Rayo VallecanoBarcelona 0-1 Rayo Vallecano | Spanish La Liga |
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