| 1 | Tue 17 Sep | 371-3 v JuventusJuventus 3-1 PSV Eindhoven |
| 2 | Tue 1 Oct | 371-1 v Sporting CPPSV Eindhoven 1-1 Sporting CP |
| 3 | Tue 22 Oct | 37 1-1 v Paris St GermainParis St Germain 1-1 PSV Eindhoven |
| 4 | Wed 27 Nov | 373-2 v Shakhtar DonetskPSV Eindhoven 3-2 Shakhtar Donetsk |
| 5 | Tue 10 Dec | 370-1 v BrestBrest 1-0 PSV Eindhoven |
| 6 | Tue 21 Jan | 373-2 v Crvena ZvezdaCrvena Zvezda 2-3 PSV Eindhoven |
| 7 | Wed 29 Jan | 373-2 v LiverpoolPSV Eindhoven 3-2 Liverpool |
| 8 | Tue 11 Feb | 371-2 v JuventusJuventus 2-1 PSV Eindhoven |
| 9 | Wed 19 Feb | 373-1 v JuventusPSV Eindhoven 3-1 Juventus |
| 10 | Tue 4 Mar | 371-7 v ArsenalPSV Eindhoven 1-7 Arsenal |
| 11 | Wed 12 Mar | 372-2 v ArsenalArsenal 2-2 PSV Eindhoven |
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