| 1 | Sat 14 Aug 2021 | 2 1-0 v Coventry CityBarnsley 1-0 Coventry City |
| 2 | Sat 16 Oct 2021 | 20-1 v ReadingReading 1-0 Barnsley |
| 3 | Wed 20 Oct 2021 | 20-2 v MiddlesbroughMiddlesbrough 2-0 Barnsley |
| 4 | Sat 30 Oct 2021 | 21-2 v Bristol CityBristol City 2-1 Barnsley |
| 5 | Wed 3 Nov 2021 | 22-1 v Derby CountyBarnsley 2-1 Derby County |
| 6 | Sat 6 Nov 2021 | 20-2 v Hull CityBarnsley 0-2 Hull City |
| 7 | Sat 20 Nov 2021 | 21-4 v FulhamFulham 4-1 Barnsley |
| 8 | Wed 24 Nov 2021 | 20-2 v Swansea CityBarnsley 0-2 Swansea City |
| 9 | Sat 27 Nov 2021 | 20-0 v Peterborough UnitedPeterborough United 0-0 Barnsley |
| 10 | Sat 4 Dec 2021 | 21-1 v Huddersfield TownBarnsley 1-1 Huddersfield Town |
| 11 | Fri 17 Dec 2021 | 20-0 v West Bromwich AlbionBarnsley 0-0 West Bromwich Albion |
| 12 | Sat 22 Jan 2022 | 21-2 v Birmingham CityBirmingham City 2-1 Barnsley |
| 13 | Tue 25 Jan 2022 | 20-3 v Nottingham ForestNottingham Forest 3-0 Barnsley |
| 14 | Sat 29 Jan 2022 | 20-1 v AFC BournemouthBarnsley 0-1 AFC Bournemouth |
| 15 | Wed 2 Feb 2022 | 2 0-1 v Cardiff CityBarnsley 0-1 Cardiff City |
| 16 | Tue 8 Feb 2022 | 21-2 v Luton TownLuton Town 2-1 Barnsley |
| 17 | Sat 12 Feb 2022 | 21-0 v Queens Park RangersBarnsley 1-0 Queens Park Rangers |
| 18 | Sat 19 Feb 2022 | 20-1 v Coventry CityCoventry City 1-0 Barnsley |
| 19 | Tue 22 Feb 2022 | 22-0 v Hull CityHull City 0-2 Barnsley |
| 20 | Sat 26 Feb 2022 | 23-2 v MiddlesbroughBarnsley 3-2 Middlesbrough |
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