| 1 | Sun 20 Aug | 264-1 v Mainz 051 FC Union Berlin 4-1 Mainz 05 | German Bundesliga |
| 2 | Sat 26 Aug | 264-1 v Darmstadt 98Darmstadt 98 1-4 1 FC Union Berlin | German Bundesliga |
| 3 | Sun 3 Sep | 260-3 v RB Leipzig1 FC Union Berlin 0-3 RB Leipzig | German Bundesliga |
| 4 | Sat 23 Sep | 260-2 v 1899 Hoffenheim1 FC Union Berlin 0-2 1899 Hoffenheim | German Bundesliga |
| 5 | Sat 30 Sep | 260-1 v 1 FC Heidenheim1 FC Heidenheim 1-0 1 FC Union Berlin | German Bundesliga |
| 6 | Tue 3 Oct | 262-3 v Sporting Braga1 FC Union Berlin 2-3 Sporting Braga | UEFA Champions League Group C |
| 7 | Sat 7 Oct | 262-4 v Borussia DortmundBorussia Dortmund 4-2 1 FC Union Berlin | German Bundesliga |
| 8 | Sat 28 Oct | 260-2 v Werder BremenWerder Bremen 2-0 1 FC Union Berlin | German Bundesliga |
| 9 | Wed 8 Nov | 261-1 v NapoliNapoli 1-1 1 FC Union Berlin | UEFA Champions League Group C |
| 10 | Sun 12 Nov | 260-4 v Bayer 04 LeverkusenBayer 04 Leverkusen 4-0 1 FC Union Berlin | German Bundesliga |
| 11 | Sat 25 Nov | 261-1 v FC Augsburg1 FC Union Berlin 1-1 FC Augsburg | German Bundesliga |
| 12 | Wed 29 Nov | 261-1 v Sporting BragaSporting Braga 1-1 1 FC Union Berlin | UEFA Champions League Group C |
| 13 | Sat 9 Dec | 263-1 v Borussia Mönchengladbach1 FC Union Berlin 3-1 Borussia Mönchengladbach | German Bundesliga |
| 14 | Tue 12 Dec | 262-3 v Real Madrid1 FC Union Berlin 2-3 Real Madrid | UEFA Champions League Group C |
| 15 | Sat 16 Dec | 26 0-3 v VfL BochumVfL Bochum 3-0 1 FC Union Berlin | German Bundesliga |
| 16 | Wed 20 Dec | 262-0 v 1 FC Köln1 FC Union Berlin 2-0 1 FC Köln | German Bundesliga |
| 17 | Sat 13 Jan | 260-0 v SC FreiburgSC Freiburg 0-0 1 FC Union Berlin | German Bundesliga |
| 18 | Wed 24 Jan | 260-1 v Bayern MunichBayern Munich 1-0 1 FC Union Berlin | German Bundesliga |
| 19 | Wed 7 Feb | 261-1 v Mainz 05Mainz 05 1-1 1 FC Union Berlin | German Bundesliga |
| 20 | Sat 10 Feb | 26 1-0 v VfL Wolfsburg1 FC Union Berlin 1-0 VfL Wolfsburg | German Bundesliga |
| 21 | Sat 17 Feb | 261-0 v 1899 Hoffenheim1899 Hoffenheim 0-1 1 FC Union Berlin | German Bundesliga |
| 22 | Sat 24 Feb | 262-2 v 1 FC Heidenheim1 FC Union Berlin 2-2 1 FC Heidenheim | German Bundesliga |
| 23 | Sat 2 Mar | 260-2 v Borussia Dortmund1 FC Union Berlin 0-2 Borussia Dortmund | German Bundesliga |
| 24 | Fri 8 Mar | 260-2 v VfB StuttgartVfB Stuttgart 2-0 1 FC Union Berlin | German Bundesliga |
| 25 | Sat 16 Mar | 262-1 v Werder Bremen1 FC Union Berlin 2-1 Werder Bremen | German Bundesliga |
| 26 | Sat 30 Mar | 260-0 v Eintracht FrankfurtEintracht Frankfurt 0-0 1 FC Union Berlin | German Bundesliga |
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