| 1 | Tue 8 Aug | 324-1 v Sturm GrazPSV Eindhoven 4-1 Sturm Graz | UEFA Champions League Third Qualifying Round |
| 2 | Sat 12 Aug | 322-0 v FC UtrechtPSV Eindhoven 2-0 FC Utrecht | Dutch Eredivisie |
| 3 | Tue 15 Aug | 323-1 v Sturm GrazSturm Graz 1-3 PSV Eindhoven | UEFA Champions League Third Qualifying Round |
| 4 | Sat 19 Aug | 323-1 v VitesseVitesse 1-3 PSV Eindhoven | Dutch Eredivisie |
| 5 | Tue 22 Aug | 32 2-2 v RangersRangers 2-2 PSV Eindhoven | UEFA Champions League Play-off Qualifying Play-off Round |
| 6 | Wed 30 Aug | 325-1 v RangersPSV Eindhoven 5-1 Rangers | UEFA Champions League Play-off Qualifying Play-off Round |
| 7 | Sat 2 Sep | 324-0 v RKC WaalwijkRKC Waalwijk 0-4 PSV Eindhoven | Dutch Eredivisie |
| 8 | Wed 20 Sep | 320-4 v ArsenalArsenal 4-0 PSV Eindhoven | UEFA Champions League Group B |
| 9 | Sat 23 Sep | 324-0 v Almere CityAlmere City 0-4 PSV Eindhoven | Dutch Eredivisie |
| 10 | Wed 27 Sep | 323-0 v Go Ahead EaglesPSV Eindhoven 3-0 Go Ahead Eagles | Dutch Eredivisie |
| 11 | Sat 30 Sep | 323-1 v VolendamPSV Eindhoven 3-1 Volendam | Dutch Eredivisie |
| 12 | Sun 8 Oct | 324-0 v Sparta RotterdamSparta Rotterdam 0-4 PSV Eindhoven | Dutch Eredivisie |
| 13 | Sat 21 Oct | 323-1 v Fortuna SittardPSV Eindhoven 3-1 Fortuna Sittard | Dutch Eredivisie |
| 14 | Tue 24 Oct | 321-1 v LensLens 1-1 PSV Eindhoven | UEFA Champions League Group B |
| 15 | Sun 29 Oct | 325-2 v AjaxPSV Eindhoven 5-2 Ajax | Dutch Eredivisie |
| 16 | Sat 4 Nov | 326-0 v Heracles AlmeloHeracles Almelo 0-6 PSV Eindhoven | Dutch Eredivisie |
| 17 | Wed 8 Nov | 321-0 v LensPSV Eindhoven 1-0 Lens | UEFA Champions League Group B |
| 18 | Sun 12 Nov | 324-0 v PEC ZwollePSV Eindhoven 4-0 PEC Zwolle | Dutch Eredivisie |
| 19 | Wed 29 Nov | 323-2 v SevillaSevilla 2-3 PSV Eindhoven | UEFA Champions League Group B |
| 20 | Sun 3 Dec | 322-1 v FeyenoordFeyenoord 1-2 PSV Eindhoven | Dutch Eredivisie |
| 21 | Thu 7 Dec | 322-0 v sc HeerenveenPSV Eindhoven 2-0 sc Heerenveen | Dutch Eredivisie |
| 22 | Tue 12 Dec | 321-1 v ArsenalPSV Eindhoven 1-1 Arsenal | UEFA Champions League Group B |
| 23 | Sun 17 Dec | 324-0 v AZ AlkmaarAZ Alkmaar 0-4 PSV Eindhoven | Dutch Eredivisie |
| 24 | Sat 13 Jan | 323-1 v Excelsior RotterdamPSV Eindhoven 3-1 Excelsior Rotterdam | Dutch Eredivisie |
| 25 | Sun 21 Jan | 321-1 v FC UtrechtFC Utrecht 1-1 PSV Eindhoven | Dutch Eredivisie |
| 26 | Sat 27 Jan | 322-0 v Almere CityPSV Eindhoven 2-0 Almere City | Dutch Eredivisie |
| 27 | Sun 4 Feb | 140-2 v RB LeipzigRB Leipzig 2-0 1 FC Union Berlin | German Bundesliga |
| 28 | Wed 7 Feb | 141-1 v Mainz 05Mainz 05 1-1 1 FC Union Berlin | German Bundesliga |
| 29 | Sat 17 Feb | 141-0 v 1899 Hoffenheim1899 Hoffenheim 0-1 1 FC Union Berlin | German Bundesliga |
| 30 | Sat 24 Feb | 142-2 v 1 FC Heidenheim1 FC Union Berlin 2-2 1 FC Heidenheim | German Bundesliga |
| 31 | Fri 8 Mar | 140-2 v VfB StuttgartVfB Stuttgart 2-0 1 FC Union Berlin | German Bundesliga |
| 32 | Sat 16 Mar | 142-1 v Werder Bremen1 FC Union Berlin 2-1 Werder Bremen | German Bundesliga |
| 33 | Sat 30 Mar | 140-0 v Eintracht FrankfurtEintracht Frankfurt 0-0 1 FC Union Berlin | German Bundesliga |
| 34 | Sat 6 Apr | 140-1 v Bayer 04 Leverkusen1 FC Union Berlin 0-1 Bayer 04 Leverkusen | German Bundesliga |
| 35 | Sat 20 Apr | 141-5 v Bayern Munich1 FC Union Berlin 1-5 Bayern Munich | German Bundesliga |
| 36 | Sun 28 Apr | 140-0 v Borussia MönchengladbachBorussia Mönchengladbach 0-0 1 FC Union Berlin | German Bundesliga |
| 37 | Sun 5 May | 143-4 v VfL Bochum1 FC Union Berlin 3-4 VfL Bochum | German Bundesliga |
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