| 1 | Tue 22 Aug | 82-2 v RangersRangers 2-2 PSV Eindhoven | UEFA Champions League Play-off Qualifying Play-off Round |
| 2 | Wed 30 Aug | 85-1 v RangersPSV Eindhoven 5-1 Rangers | UEFA Champions League Play-off Qualifying Play-off Round |
| 3 | Sat 2 Sep | 84-0 v RKC WaalwijkRKC Waalwijk 0-4 PSV Eindhoven | Dutch Eredivisie |
| 4 | Sat 9 Sep | 23-0 v UzbekistanUSA 3-0 Uzbekistan | International Friendly |
| 5 | Wed 13 Sep | 24-0 v OmanUSA 4-0 Oman | International Friendly |
| 6 | Sat 16 Sep | 84-0 v NEC NijmegenPSV Eindhoven 4-0 NEC Nijmegen | Dutch Eredivisie |
| 7 | Wed 20 Sep | 80-4 v ArsenalArsenal 4-0 PSV Eindhoven | UEFA Champions League Group B |
| 8 | Sat 23 Sep | 84-0 v Almere CityAlmere City 0-4 PSV Eindhoven | Dutch Eredivisie |
| 9 | Tue 3 Oct | 82-2 v SevillaPSV Eindhoven 2-2 Sevilla | UEFA Champions League Group B |
| 10 | Sun 8 Oct | 8 4-0 v Sparta RotterdamSparta Rotterdam 0-4 PSV Eindhoven | Dutch Eredivisie |
| 11 | Sat 14 Oct | 21-3 v GermanyUSA 1-3 Germany | International Friendly |
| 12 | Wed 18 Oct | 24-0 v GhanaUSA 4-0 Ghana | International Friendly |
| 13 | Tue 24 Oct | 81-1 v LensLens 1-1 PSV Eindhoven | UEFA Champions League Group B |
| 14 | Sun 29 Oct | 85-2 v AjaxPSV Eindhoven 5-2 Ajax | Dutch Eredivisie |
| 15 | Sat 4 Nov | 86-0 v Heracles AlmeloHeracles Almelo 0-6 PSV Eindhoven | Dutch Eredivisie |
| 16 | Wed 8 Nov | 81-0 v LensPSV Eindhoven 1-0 Lens | UEFA Champions League Group B |
| 17 | Sun 12 Nov | 84-0 v PEC ZwollePSV Eindhoven 4-0 PEC Zwolle | Dutch Eredivisie |
| 18 | Sat 25 Nov | 83-0 v FC TwenteFC Twente 0-3 PSV Eindhoven | Dutch Eredivisie |
| 19 | Wed 29 Nov | 83-2 v SevillaSevilla 2-3 PSV Eindhoven | UEFA Champions League Group B |
| 20 | Sun 3 Dec | 82-1 v FeyenoordFeyenoord 1-2 PSV Eindhoven | Dutch Eredivisie |
| 21 | Thu 7 Dec | 82-0 v sc HeerenveenPSV Eindhoven 2-0 sc Heerenveen | Dutch Eredivisie |
| 22 | Tue 12 Dec | 81-1 v ArsenalPSV Eindhoven 1-1 Arsenal | UEFA Champions League Group B |
| 23 | Sun 17 Dec | 84-0 v AZ AlkmaarAZ Alkmaar 0-4 PSV Eindhoven | Dutch Eredivisie |
| 24 | Sat 13 Jan | 83-1 v Excelsior RotterdamPSV Eindhoven 3-1 Excelsior Rotterdam | Dutch Eredivisie |
| 25 | Sun 21 Jan | 81-1 v FC UtrechtFC Utrecht 1-1 PSV Eindhoven | Dutch Eredivisie |
| 26 | Sat 27 Jan | 82-0 v Almere CityPSV Eindhoven 2-0 Almere City | Dutch Eredivisie |
| 27 | Sat 3 Feb | 81-1 v AjaxAjax 1-1 PSV Eindhoven | Dutch Eredivisie |
| 28 | Sun 11 Feb | 85-1 v VolendamVolendam 1-5 PSV Eindhoven | Dutch Eredivisie |
| 29 | Fri 16 Feb | 82-0 v Heracles AlmeloPSV Eindhoven 2-0 Heracles Almelo | Dutch Eredivisie |
| 30 | Tue 20 Feb | 81-1 v Borussia DortmundPSV Eindhoven 1-1 Borussia Dortmund | UEFA Champions League Round of 16 |
| 31 | Sat 24 Feb | 87-1 v PEC ZwollePEC Zwolle 1-7 PSV Eindhoven | Dutch Eredivisie |
| 32 | Sun 3 Mar | 82-2 v FeyenoordPSV Eindhoven 2-2 Feyenoord | Dutch Eredivisie |
| 33 | Fri 8 Mar | 81-0 v Go Ahead EaglesGo Ahead Eagles 0-1 PSV Eindhoven | Dutch Eredivisie |
| 34 | Wed 13 Mar | 80-2 v Borussia DortmundBorussia Dortmund 2-0 PSV Eindhoven | UEFA Champions League Round of 16 |
| 35 | Sun 17 Mar | 81-0 v FC TwentePSV Eindhoven 1-0 FC Twente | Dutch Eredivisie |
| 36 | Sat 30 Mar | 81-3 v NEC NijmegenNEC Nijmegen 3-1 PSV Eindhoven | Dutch Eredivisie |
| 37 | Tue 2 Apr | 82-0 v Excelsior RotterdamExcelsior Rotterdam 0-2 PSV Eindhoven | Dutch Eredivisie |
| 38 | Sat 6 Apr | 85-1 v AZ AlkmaarPSV Eindhoven 5-1 AZ Alkmaar | Dutch Eredivisie |
| 39 | Sat 13 Apr | 86-0 v VitessePSV Eindhoven 6-0 Vitesse | Dutch Eredivisie |
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