| 1 | Sat 17 Aug 2019 | 210-3 v SC FreiburgSC Freiburg 3-0 Mainz 05 |
| 2 | Sat 24 Aug 2019 | 21 1-3 v Borussia MönchengladbachMainz 05 1-3 Borussia Mönchengladbach |
| 3 | Sat 31 Aug 2019 | 211-6 v Bayern MunichBayern Munich 6-1 Mainz 05 |
| 4 | Sat 14 Sep 2019 | 212-1 v Hertha BerlinMainz 05 2-1 Hertha Berlin |
| 5 | Fri 20 Sep 2019 | 211-2 v FC Schalke 04FC Schalke 04 2-1 Mainz 05 |
| 6 | Sat 28 Sep 2019 | 210-1 v VfL WolfsburgMainz 05 0-1 VfL Wolfsburg |
| 7 | Sat 5 Oct 2019 | 212-1 v SC Paderborn 07SC Paderborn 07 1-2 Mainz 05 |
| 8 | Sat 19 Oct 2019 | 210-1 v Fortuna DüsseldorfFortuna Düsseldorf 1-0 Mainz 05 |
| 9 | Fri 25 Oct 2019 | 213-1 v 1. FC KölnMainz 05 3-1 1. FC Köln |
| 10 | Sat 9 Nov 2019 | 212-3 v 1. FC Union BerlinMainz 05 2-3 1. FC Union Berlin |
| 11 | Sun 24 Nov 2019 | 21 5-1 v 1899 Hoffenheim1899 Hoffenheim 1-5 Mainz 05 |
| 12 | Mon 2 Dec 2019 | 212-1 v Eintracht FrankfurtMainz 05 2-1 Eintracht Frankfurt |
| 13 | Sat 7 Dec 2019 | 211-2 v FC AugsburgFC Augsburg 2-1 Mainz 05 |
| 14 | Sat 21 Dec 2019 | 210-1 v Bayer 04 LeverkusenMainz 05 0-1 Bayer 04 Leverkusen |
| 15 | Sat 18 Jan 2020 | 211-2 v SC FreiburgMainz 05 1-2 SC Freiburg |
| 16 | Sat 25 Jan 2020 | 211-3 v Borussia MönchengladbachBorussia Mönchengladbach 3-1 Mainz 05 |
| 17 | Sat 1 Feb 2020 | 211-3 v Bayern MunichMainz 05 1-3 Bayern Munich |
| 18 | Sat 8 Feb 2020 | 213-1 v Hertha BerlinHertha Berlin 1-3 Mainz 05 |
| 19 | Sun 23 Feb 2020 | 210-4 v VfL WolfsburgVfL Wolfsburg 4-0 Mainz 05 |
| 20 | Sat 29 Feb 2020 | 21 2-0 v SC Paderborn 07Mainz 05 2-0 SC Paderborn 07 |
| 21 | Sun 8 Mar 2020 | 211-1 v Fortuna DüsseldorfMainz 05 1-1 Fortuna Düsseldorf |
| 22 | Sat 27 Jun 2020 | 210-1 v Bayer 04 LeverkusenBayer 04 Leverkusen 1-0 Mainz 05 |
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