| 1 | Sat 17 Aug | 990-0 v MonzaEmpoli 0-0 Monza |
| 2 | Sun 25 Aug | 992-1 v RomaRoma 1-2 Empoli |
| 3 | Sat 31 Aug | 991-1 v BolognaBologna 1-1 Empoli |
| 4 | Sat 14 Sep | 990-0 v JuventusEmpoli 0-0 Juventus |
| 5 | Fri 20 Sep | 992-0 v CagliariCagliari 0-2 Empoli |
| 6 | Sun 29 Sep | 990-0 v FiorentinaEmpoli 0-0 Fiorentina |
| 7 | Sun 6 Oct | 991-2 v LazioLazio 2-1 Empoli |
| 8 | Sun 20 Oct | 990-1 v NapoliEmpoli 0-1 Napoli |
| 9 | Mon 25 Nov | 991-1 v UdineseEmpoli 1-1 Udinese |
| 10 | Sat 30 Nov | 990-3 v AC MilanAC Milan 3-0 Empoli |
| 11 | Sun 8 Dec | 994-1 v Hellas VeronaHellas Verona 1-4 Empoli |
| 12 | Sun 22 Dec | 992-3 v AtalantaAtalanta 3-2 Empoli |
| 13 | Sat 28 Dec | 991-2 v GenoaEmpoli 1-2 Genoa |
| 14 | Sat 4 Jan | 99 1-1 v VeneziaVenezia 1-1 Empoli |
| 15 | Sat 11 Jan | 991-3 v LecceEmpoli 1-3 Lecce |
| 16 | Sun 19 Jan | 991-3 v Inter MilanInter Milan 3-1 Empoli |
| 17 | Sat 25 Jan | 991-1 v BolognaEmpoli 1-1 Bologna |
| 18 | Sun 2 Feb | 991-4 v JuventusJuventus 4-1 Empoli |
| 19 | Sat 8 Feb | 990-2 v AC MilanEmpoli 0-2 AC Milan |
| 20 | Sun 16 Feb | 990-3 v UdineseUdinese 3-0 Empoli |
| 21 | Sun 23 Feb | 990-5 v AtalantaEmpoli 0-5 Atalanta |
| 22 | Sun 2 Mar | 991-1 v GenoaGenoa 1-1 Empoli |
| 23 | Sun 9 Mar | 990-1 v RomaEmpoli 0-1 Roma |
| 24 | Sat 15 Mar | 990-1 v TorinoTorino 1-0 Empoli |
| 25 | Sat 29 Mar | 991-1 v Como 1907Como 1907 1-1 Empoli |
| 26 | Sun 6 Apr | 990-0 v CagliariEmpoli 0-0 Cagliari |
| 27 | Mon 14 Apr | 990-3 v NapoliNapoli 3-0 Empoli |
| 28 | Sun 20 Apr | 992-2 v VeneziaEmpoli 2-2 Venezia |
| 29 | Sun 27 Apr | 991-2 v FiorentinaFiorentina 2-1 Empoli |
| 30 | Sat 10 May | 992-1 v ParmaEmpoli 2-1 Parma |
| 31 | Sun 18 May | 993-1 v MonzaMonza 1-3 Empoli |
| 32 | Sun 25 May | 991-2 v Hellas VeronaEmpoli 1-2 Hellas Verona |
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