| 1 | Sat 17 Aug 2019 | 95-1 v FC AugsburgBorussia Dortmund 5-1 FC Augsburg | German Bundesliga |
| 2 | Fri 23 Aug 2019 | 93-1 v 1. FC Köln1. FC Köln 1-3 Borussia Dortmund | German Bundesliga |
| 3 | Sat 31 Aug 2019 | 91-3 v 1. FC Union Berlin1. FC Union Berlin 3-1 Borussia Dortmund | German Bundesliga |
| 4 | Thu 5 Sep 2019 | 92-1 v RomaniaRomania 1-2 Spain | European Championship Qualification Group F |
| 5 | Sun 8 Sep 2019 | 94-0 v Faroe IslandsSpain 4-0 Faroe Islands | European Championship Qualification Group F |
| 6 | Sat 14 Sep 2019 | 94-0 v Bayer 04 LeverkusenBorussia Dortmund 4-0 Bayer 04 Leverkusen | German Bundesliga |
| 7 | Tue 17 Sep 2019 | 90-0 v BarcelonaBorussia Dortmund 0-0 Barcelona | UEFA Champions League Group F |
| 8 | Sun 22 Sep 2019 | 92-2 v Eintracht FrankfurtEintracht Frankfurt 2-2 Borussia Dortmund | German Bundesliga |
| 9 | Sat 28 Sep 2019 | 92-2 v Werder BremenBorussia Dortmund 2-2 Werder Bremen | German Bundesliga |
| 10 | Sat 2 Nov 2019 | 93-0 v VfL WolfsburgBorussia Dortmund 3-0 VfL Wolfsburg | German Bundesliga |
| 11 | Tue 5 Nov 2019 | 93-2 v Inter MilanBorussia Dortmund 3-2 Inter Milan | UEFA Champions League Group F |
| 12 | Sat 9 Nov 2019 | 90-4 v Bayern MunichBayern Munich 4-0 Borussia Dortmund | German Bundesliga |
| 13 | Fri 15 Nov 2019 | 97-0 v MaltaSpain 7-0 Malta | European Championship Qualification Group F |
| 14 | Mon 18 Nov 2019 | 95-0 v RomaniaSpain 5-0 Romania | European Championship Qualification Group F |
| 15 | Fri 22 Nov 2019 | 93-3 v SC Paderborn 07Borussia Dortmund 3-3 SC Paderborn 07 | German Bundesliga |
| 16 | Sat 14 Dec 2019 | 94-0 v Mainz 05Mainz 05 0-4 Borussia Dortmund | German Bundesliga |
| 17 | Fri 20 Dec 2019 | 91-2 v 1899 Hoffenheim1899 Hoffenheim 2-1 Borussia Dortmund | German Bundesliga |
| 18 | Sat 8 Feb 2020 | 1-1 v Real ValladolidReal Valladolid 1-1 Villarreal | Spanish La Liga |
| 19 | Sat 15 Feb 2020 | 2-1 v LevanteVillarreal 2-1 Levante | Spanish La Liga |
| 20 | Sun 23 Feb 2020 | 1-3 v Atlético MadridAtlético Madrid 3-1 Villarreal | Spanish La Liga |
| 21 | Sun 1 Mar 2020 | 0-1 v Athletic BilbaoAthletic Bilbao 1-0 Villarreal | Spanish La Liga |
| 22 | Sun 8 Mar 2020 | 1-2 v LeganésVillarreal 1-2 Leganés | Spanish La Liga |
| 23 | Sun 28 Jun 2020 | 172-0 v ValenciaVillarreal 2-0 Valencia | Spanish La Liga |
| 24 | Wed 1 Jul 2020 | 172-0 v Real BetisReal Betis 0-2 Villarreal | Spanish La Liga |
| 25 | Sun 5 Jul 2020 | 171-4 v BarcelonaVillarreal 1-4 Barcelona | Spanish La Liga |
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