| 1 | Sat 17 Aug 2019 | 0-3 v SC FreiburgSC Freiburg 3-0 Mainz 05 | German Bundesliga |
| 2 | Sat 24 Aug 2019 | 1-3 v Borussia MönchengladbachMainz 05 1-3 Borussia Mönchengladbach | German Bundesliga |
| 3 | Sat 31 Aug 2019 | 1-6 v Bayern MunichBayern Munich 6-1 Mainz 05 | German Bundesliga |
| 4 | Thu 5 Sep 2019 | 111-1 v Republic of IrelandRepublic of Ireland 1-1 Switzerland | European Championship Qualification Group D |
| 5 | Sun 8 Sep 2019 | 114-0 v GibraltarSwitzerland 4-0 Gibraltar | European Championship Qualification Group D |
| 6 | Sat 14 Sep 2019 | 2-1 v Hertha BerlinMainz 05 2-1 Hertha Berlin | German Bundesliga |
| 7 | Fri 20 Sep 2019 | 1-2 v FC Schalke 04FC Schalke 04 2-1 Mainz 05 | German Bundesliga |
| 8 | Sat 28 Sep 2019 | 0-1 v VfL WolfsburgMainz 05 0-1 VfL Wolfsburg | German Bundesliga |
| 9 | Sat 5 Oct 2019 | 2-1 v SC Paderborn 07SC Paderborn 07 1-2 Mainz 05 | German Bundesliga |
| 10 | Tue 15 Oct 2019 | 112-0 v Republic of IrelandSwitzerland 2-0 Republic of Ireland | European Championship Qualification Group D |
| 11 | Sat 19 Oct 2019 | 0-1 v Fortuna DüsseldorfFortuna Düsseldorf 1-0 Mainz 05 | German Bundesliga |
| 12 | Sat 9 Nov 2019 | 2-3 v 1. FC Union BerlinMainz 05 2-3 1. FC Union Berlin | German Bundesliga |
| 13 | Fri 15 Nov 2019 | 111-0 v GeorgiaSwitzerland 1-0 Georgia | European Championship Qualification Group D |
| 14 | Sun 24 Nov 2019 | 5-1 v 1899 Hoffenheim1899 Hoffenheim 1-5 Mainz 05 | German Bundesliga |
| 15 | Mon 2 Dec 2019 | 2-1 v Eintracht FrankfurtMainz 05 2-1 Eintracht Frankfurt | German Bundesliga |
| 16 | Sat 7 Dec 2019 | 1-2 v FC AugsburgFC Augsburg 2-1 Mainz 05 | German Bundesliga |
| 17 | Sat 14 Dec 2019 | 0-4 v Borussia DortmundMainz 05 0-4 Borussia Dortmund | German Bundesliga |
| 18 | Tue 17 Dec 2019 | 5-0 v Werder BremenWerder Bremen 0-5 Mainz 05 | German Bundesliga |
| 19 | Sat 21 Dec 2019 | 0-1 v Bayer 04 LeverkusenMainz 05 0-1 Bayer 04 Leverkusen | German Bundesliga |
| 20 | Sat 29 Feb 2020 | 2-0 v SC Paderborn 07Mainz 05 2-0 SC Paderborn 07 | German Bundesliga |
| 21 | Sun 8 Mar 2020 | 1-1 v Fortuna DüsseldorfMainz 05 1-1 Fortuna Düsseldorf | German Bundesliga |
| 22 | Sat 27 Jun 2020 | 200-1 v Bayer 04 LeverkusenBayer 04 Leverkusen 1-0 Mainz 05 | German Bundesliga |
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