| 1 | Fri 23 Aug 2019 | 1-2 v LevanteLevante 2-1 Villarreal | Spanish La Liga |
| 2 | Sun 1 Sep 2019 | 2-2 v Real MadridVillarreal 2-2 Real Madrid | Spanish La Liga |
| 3 | Sat 14 Sep 2019 | 3-0 v LeganésLeganés 0-3 Villarreal | Spanish La Liga |
| 4 | Sat 21 Sep 2019 | 2-0 v Real ValladolidVillarreal 2-0 Real Valladolid | Spanish La Liga |
| 5 | Tue 24 Sep 2019 | 1-2 v BarcelonaBarcelona 2-1 Villarreal | Spanish La Liga |
| 6 | Fri 27 Sep 2019 | 5-1 v Real BetisVillarreal 5-1 Real Betis | Spanish La Liga |
| 7 | Sat 5 Oct 2019 | 1-2 v OsasunaOsasuna 2-1 Villarreal | Spanish La Liga |
| 8 | Sat 12 Oct 2019 | 31-1 v NorwayNorway 1-1 Spain | European Championship Qualification Group F |
| 9 | Sun 20 Oct 2019 | 1-0 v EspanyolEspanyol 0-1 Villarreal | Spanish La Liga |
| 10 | Fri 25 Oct 2019 | 4-1 v AlavésVillarreal 4-1 Alavés | Spanish La Liga |
| 11 | Thu 31 Oct 2019 | 1-2 v EibarEibar 2-1 Villarreal | Spanish La Liga |
| 12 | Sun 3 Nov 2019 | 0-0 v Athletic BilbaoVillarreal 0-0 Athletic Bilbao | Spanish La Liga |
| 13 | Sun 10 Nov 2019 | 1-3 v MallorcaMallorca 3-1 Villarreal | Spanish La Liga |
| 14 | Fri 15 Nov 2019 | 37-0 v MaltaSpain 7-0 Malta | European Championship Qualification Group F |
| 15 | Mon 18 Nov 2019 | 35-0 v RomaniaSpain 5-0 Romania | European Championship Qualification Group F |
| 16 | Sat 30 Nov 2019 | 1-2 v ValenciaValencia 2-1 Villarreal | Spanish La Liga |
| 17 | Fri 6 Dec 2019 | 0-0 v Atlético MadridVillarreal 0-0 Atlético Madrid | Spanish La Liga |
| 18 | Sun 15 Dec 2019 | 2-1 v SevillaSevilla 1-2 Villarreal | Spanish La Liga |
| 19 | Sat 21 Dec 2019 | 1-0 v GetafeVillarreal 1-0 Getafe | Spanish La Liga |
| 20 | Sun 5 Jan 2020 | 2-1 v Real SociedadReal Sociedad 1-2 Villarreal | Spanish La Liga |
| 21 | Sun 19 Jan 2020 | 1-2 v EspanyolVillarreal 1-2 Espanyol | Spanish La Liga |
| 22 | Sat 25 Jan 2020 | 2-1 v AlavésAlavés 1-2 Villarreal | Spanish La Liga |
| 23 | Sat 8 Feb 2020 | 1-1 v Real ValladolidReal Valladolid 1-1 Villarreal | Spanish La Liga |
| 24 | Sat 15 Feb 2020 | 2-1 v LevanteVillarreal 2-1 Levante | Spanish La Liga |
| 25 | Sun 23 Feb 2020 | 1-3 v Atlético MadridAtlético Madrid 3-1 Villarreal | Spanish La Liga |
| 26 | Sun 1 Mar 2020 | 0-1 v Athletic BilbaoAthletic Bilbao 1-0 Villarreal | Spanish La Liga |
| 27 | Sun 8 Mar 2020 | 1-2 v LeganésVillarreal 1-2 Leganés | Spanish La Liga |
| 28 | Sun 28 Jun 2020 | 32-0 v ValenciaVillarreal 2-0 Valencia | Spanish La Liga |
| 29 | Wed 1 Jul 2020 | 32-0 v Real BetisReal Betis 0-2 Villarreal | Spanish La Liga |
| 30 | Sun 5 Jul 2020 | 31-4 v BarcelonaVillarreal 1-4 Barcelona | Spanish La Liga |
| 31 | Wed 8 Jul 2020 | 33-1 v GetafeGetafe 1-3 Villarreal | Spanish La Liga |
| 32 | Mon 13 Jul 2020 | 31-2 v Real SociedadVillarreal 1-2 Real Sociedad | Spanish La Liga |
| 33 | Sun 19 Jul 2020 | 34-0 v EibarVillarreal 4-0 Eibar | Spanish La Liga |
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