| 1 | Tue 15 Sep 2020 | 233-1 v Burton AlbionBurton Albion 1-3 Aston Villa | Carabao Cup Second Round |
| 2 | Thu 1 Oct 2020 | 230-1 v Stoke CityAston Villa 0-1 Stoke City | Carabao Cup Fourth Round |
| 3 | Sat 17 Oct 2020 | 41-1 v Gil VicenteGil Vicente 1-1 Tondela | Portuguese Primeira Liga |
| 4 | Sun 18 Oct 2020 | 240-2 v ElcheAlavés 0-2 Elche | Spanish La Liga |
| 5 | Sun 25 Oct 2020 | 242-0 v Real ValladolidReal Valladolid 0-2 Alavés | Spanish La Liga |
| 6 | Sat 31 Oct 2020 | 24 1-1 v BarcelonaAlavés 1-1 Barcelona | Spanish La Liga |
| 7 | Sun 22 Nov 2020 | 242-2 v ValenciaAlavés 2-2 Valencia | Spanish La Liga |
| 8 | Sat 28 Nov 2020 | 242-1 v Real MadridReal Madrid 1-2 Alavés | Spanish La Liga |
| 9 | Sat 5 Dec 2020 | 400-2 v Atlético MadridAtlético Madrid 2-0 Real Valladolid | Spanish La Liga |
| 10 | Sun 6 Dec 2020 | 240-0 v Real SociedadAlavés 0-0 Real Sociedad | Spanish La Liga |
| 11 | Sat 12 Dec 2020 | 24 0-1 v HuescaHuesca 1-0 Alavés | Spanish La Liga |
| 12 | Sun 20 Dec 2020 | 240-2 v Celta VigoCelta Vigo 2-0 Alavés | Spanish La Liga |
| 13 | Tue 22 Dec 2020 | 400-3 v BarcelonaReal Valladolid 0-3 Barcelona | Spanish La Liga |
| 14 | Wed 23 Dec 2020 | 242-1 v EibarAlavés 2-1 Eibar | Spanish La Liga |
| 15 | Thu 31 Dec 2020 | 24 1-1 v OsasunaOsasuna 1-1 Alavés | Spanish La Liga |
| 16 | Sat 2 Jan 2021 | 401-0 v GetafeGetafe 0-1 Real Valladolid | Spanish La Liga |
| 17 | Sun 3 Jan 2021 | 241-2 v Atlético MadridAlavés 1-2 Atlético Madrid | Spanish La Liga |
| 18 | Sun 10 Jan 2021 | 241-3 v CádizCádiz 3-1 Alavés | Spanish La Liga |
| 19 | Sun 10 Jan 2021 | 400-1 v ValenciaReal Valladolid 0-1 Valencia | Spanish La Liga |
| 20 | Tue 19 Jan 2021 | 241-2 v SevillaAlavés 1-2 Sevilla | Spanish La Liga |
| 21 | Sun 31 Jan 2021 | 240-0 v GetafeGetafe 0-0 Alavés | Spanish La Liga |
| 22 | Sat 13 Feb 2021 | 401-1 v EibarEibar 1-1 Real Valladolid | Spanish La Liga |
| 23 | Sun 21 Mar 2021 | 24 0-1 v Atlético MadridAtlético Madrid 1-0 Alavés | Spanish La Liga |
| 24 | Sun 4 Apr 2021 | 241-3 v Celta VigoAlavés 1-3 Celta Vigo | Spanish La Liga |
| 25 | Sat 10 Apr 2021 | 240-0 v Athletic BilbaoAthletic Bilbao 0-0 Alavés | Spanish La Liga |
| 26 | Sun 18 Apr 2021 | 241-0 v HuescaAlavés 1-0 Huesca | Spanish La Liga |
| 27 | Wed 21 Apr 2021 | 242-1 v VillarrealAlavés 2-1 Villarreal | Spanish La Liga |
| 28 | Sat 24 Apr 2021 | 241-1 v ValenciaValencia 1-1 Alavés | Spanish La Liga |
| 29 | Sat 1 May 2021 | 240-3 v EibarEibar 3-0 Alavés | Spanish La Liga |
| 30 | Sat 8 May 2021 | 242-2 v LevanteAlavés 2-2 Levante | Spanish La Liga |
| 31 | Sun 9 May 2021 | 400-3 v ValenciaValencia 3-0 Real Valladolid | Spanish La Liga |
| 32 | Tue 11 May 2021 | 242-0 v ElcheElche 0-2 Alavés | Spanish La Liga |
| 33 | Sun 16 May 2021 | 401-4 v Real SociedadReal Sociedad 4-1 Real Valladolid | Spanish La Liga |
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