| 1 | Thu 22 Oct 2020 | 135-3 v SivassporVillarreal 5-3 Sivasspor | Europa League Group I |
| 2 | Thu 29 Oct 2020 | 133-1 v FK QarabağFK Qarabağ 1-3 Villarreal | Europa League Group I |
| 3 | Thu 5 Nov 2020 | 134-0 v Maccabi Tel-AvivVillarreal 4-0 Maccabi Tel-Aviv | Europa League Group I |
| 4 | Thu 26 Nov 2020 | 131-1 v Maccabi Tel-AvivMaccabi Tel-Aviv 1-1 Villarreal | Europa League Group I |
| 5 | Thu 3 Dec 2020 | 131-0 v SivassporSivasspor 0-1 Villarreal | Europa League Group I |
| 6 | Thu 18 Feb 2021 | 132-0 v SV Red Bull SalzburgSV Red Bull Salzburg 0-2 Villarreal | Europa League Round of 32 |
| 7 | Thu 25 Feb 2021 | 132-1 v SV Red Bull SalzburgVillarreal 2-1 SV Red Bull Salzburg | Europa League Round of 32 |
| 8 | Thu 11 Mar 2021 | 132-0 v Dynamo KievDynamo Kiev 0-2 Villarreal | Europa League Round of 16 |
| 9 | Thu 8 Apr 2021 | 131-0 v Dinamo ZagrebDinamo Zagreb 0-1 Villarreal | Europa League Quarter Final |
| 10 | Thu 15 Apr 2021 | 132-1 v Dinamo ZagrebVillarreal 2-1 Dinamo Zagreb | Europa League Quarter Final |
| 11 | Wed 21 Apr 2021 | 131-2 v AlavésAlavés 2-1 Villarreal | Spanish La Liga |
| 12 | Thu 29 Apr 2021 | 132-1 v ArsenalVillarreal 2-1 Arsenal | Europa League Semi Final |
| 13 | Thu 6 May 2021 | 130-0 v ArsenalArsenal 0-0 Villarreal | Europa League Semi Final |
| 14 | Sat 22 May 2021 | 131-2 v Real MadridReal Madrid 2-1 Villarreal | Spanish La Liga |
| 15 | Wed 26 May 2021 | 131-1 v Manchester UnitedVillarreal 1-1 Manchester United | Europa League Final |
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