| 1 | Sun 22 Aug 2021 | 140-2 v ChelseaArsenal 0-2 Chelsea | Premier League |
| 2 | Wed 25 Aug 2021 | 146-0 v West Bromwich AlbionWest Bromwich Albion 0-6 Arsenal | Carabao Cup Second Round |
| 3 | Sat 28 Aug 2021 | 140-5 v Manchester CityManchester City 5-0 Arsenal | Premier League |
| 4 | Sat 11 Sep 2021 | 141-0 v Norwich CityArsenal 1-0 Norwich City | Premier League |
| 5 | Sat 18 Sep 2021 | 141-0 v BurnleyBurnley 0-1 Arsenal | Premier League |
| 6 | Sun 26 Sep 2021 | 143-1 v Tottenham HotspurArsenal 3-1 Tottenham Hotspur | Premier League |
| 7 | Sat 2 Oct 2021 | 140-0 v Brighton & Hove AlbionBrighton & Hove Albion 0-0 Arsenal | Premier League |
| 8 | Fri 8 Oct 2021 | 91-3 v AngolaAngola 3-1 Gabon | World Cup Qualification (Africa) Group F |
| 9 | Mon 11 Oct 2021 | 2-0 v AngolaGabon 2-0 Angola | World Cup Qualification (Africa) Group F |
| 10 | Mon 18 Oct 2021 | 142-2 v Crystal PalaceArsenal 2-2 Crystal Palace | Premier League |
| 11 | Fri 22 Oct 2021 | 14 3-1 v Aston VillaArsenal 3-1 Aston Villa | Premier League |
| 12 | Sat 30 Oct 2021 | 142-0 v Leicester CityLeicester City 0-2 Arsenal | Premier League |
| 13 | Sun 7 Nov 2021 | 14 1-0 v WatfordArsenal 1-0 Watford | Premier League |
| 14 | Fri 12 Nov 2021 | 91-0 v LibyaGabon 1-0 Libya | World Cup Qualification (Africa) Group F |
| 15 | Sat 20 Nov 2021 | 140-4 v LiverpoolLiverpool 4-0 Arsenal | Premier League |
| 16 | Sat 27 Nov 2021 | 14 2-0 v Newcastle UnitedArsenal 2-0 Newcastle United | Premier League |
| 17 | Thu 2 Dec 2021 | 142-3 v Manchester UnitedManchester United 3-2 Arsenal | Premier League |
| 18 | Mon 6 Dec 2021 | 141-2 v EvertonEverton 2-1 Arsenal | Premier League |
| 19 | Sun 6 Feb 2022 | 254-2 v Atlético MadridBarcelona 4-2 Atlético Madrid | Spanish La Liga |
| 20 | Sun 13 Feb 2022 | 252-2 v EspanyolEspanyol 2-2 Barcelona | Spanish La Liga |
| 21 | Thu 17 Feb 2022 | 251-1 v NapoliBarcelona 1-1 Napoli | UEFA Europa League Round of 32 |
| 22 | Sun 20 Feb 2022 | 254-1 v ValenciaValencia 1-4 Barcelona | Spanish La Liga |
| 23 | Thu 24 Feb 2022 | 254-2 v NapoliNapoli 2-4 Barcelona | UEFA Europa League Round of 32 |
| 24 | Sun 27 Feb 2022 | 254-0 v Athletic BilbaoBarcelona 4-0 Athletic Bilbao | Spanish La Liga |
| 25 | Sun 6 Mar 2022 | 252-1 v ElcheElche 1-2 Barcelona | Spanish La Liga |
| 26 | Thu 10 Mar 2022 | 250-0 v GalatasarayBarcelona 0-0 Galatasaray | UEFA Europa League Round of 16 |
| 27 | Sun 13 Mar 2022 | 254-0 v OsasunaBarcelona 4-0 Osasuna | Spanish La Liga |
| 28 | Thu 17 Mar 2022 | 252-1 v GalatasarayGalatasaray 1-2 Barcelona | UEFA Europa League Round of 16 |
| 29 | Sun 20 Mar 2022 | 254-0 v Real MadridReal Madrid 0-4 Barcelona | Spanish La Liga |
| 30 | Sun 3 Apr 2022 | 251-0 v SevillaBarcelona 1-0 Sevilla | Spanish La Liga |
| 31 | Thu 7 Apr 2022 | 251-1 v Eintracht FrankfurtEintracht Frankfurt 1-1 Barcelona | UEFA Europa League Quarter Final |
| 32 | Sun 10 Apr 2022 | 253-2 v LevanteLevante 2-3 Barcelona | Spanish La Liga |
| 33 | Thu 14 Apr 2022 | 252-3 v Eintracht FrankfurtBarcelona 2-3 Eintracht Frankfurt | UEFA Europa League Quarter Final |
| 34 | Mon 18 Apr 2022 | 250-1 v CádizBarcelona 0-1 Cádiz | Spanish La Liga |
| 35 | Thu 21 Apr 2022 | 251-0 v Real SociedadReal Sociedad 0-1 Barcelona | Spanish La Liga |
| 36 | Sun 24 Apr 2022 | 250-1 v Rayo VallecanoBarcelona 0-1 Rayo Vallecano | Spanish La Liga |
| 37 | Sun 1 May 2022 | 252-1 v MallorcaBarcelona 2-1 Mallorca | Spanish La Liga |
| 38 | Sat 7 May 2022 | 252-1 v Real BetisReal Betis 1-2 Barcelona | Spanish La Liga |
| 39 | Tue 10 May 2022 | 253-1 v Celta VigoBarcelona 3-1 Celta Vigo | Spanish La Liga |
| 40 | Sun 15 May 2022 | 250-0 v GetafeGetafe 0-0 Barcelona | Spanish La Liga |
| 41 | Sun 22 May 2022 | 250-2 v VillarrealBarcelona 0-2 Villarreal | Spanish La Liga |
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