| 1 | Fri 27 Aug 2021 | 70-3 v ValenciaValencia 3-0 Alavés | Spanish La Liga |
| 2 | Sat 18 Sep 2021 | 70-2 v OsasunaAlavés 0-2 Osasuna | Spanish La Liga |
| 3 | Wed 22 Sep 2021 | 70-1 v EspanyolEspanyol 1-0 Alavés | Spanish La Liga |
| 4 | Sat 25 Sep 2021 | 7 1-0 v Atlético MadridAlavés 1-0 Atlético Madrid | Spanish La Liga |
| 5 | Fri 1 Oct 2021 | 70-1 v Athletic BilbaoAthletic Bilbao 1-0 Alavés | Spanish La Liga |
| 6 | Mon 18 Oct 2021 | 70-1 v Real BetisAlavés 0-1 Real Betis | Spanish La Liga |
| 7 | Sat 30 Oct 2021 | 71-1 v BarcelonaBarcelona 1-1 Alavés | Spanish La Liga |
| 8 | Sat 27 Nov 2021 | 71-2 v Celta VigoAlavés 1-2 Celta Vigo | Spanish La Liga |
| 9 | Fri 3 Dec 2021 | 71-2 v GranadaGranada 2-1 Alavés | Spanish La Liga |
| 10 | Sat 11 Dec 2021 | 71-1 v GetafeAlavés 1-1 Getafe | Spanish La Liga |
| 11 | Sat 18 Dec 2021 | 70-2 v Rayo VallecanoRayo Vallecano 2-0 Alavés | Spanish La Liga |
| 12 | Tue 21 Dec 2021 | 72-5 v VillarrealVillarreal 5-2 Alavés | Spanish La Liga |
| 13 | Sat 5 Feb 2022 | 110-2 v Celta VigoCelta Vigo 2-0 Rayo Vallecano | Spanish La Liga |
| 14 | Sat 12 Feb 2022 | 110-3 v OsasunaRayo Vallecano 0-3 Osasuna | Spanish La Liga |
| 15 | Fri 18 Feb 2022 | 11 1-2 v ElcheElche 2-1 Rayo Vallecano | Spanish La Liga |
| 16 | Sun 6 Mar 2022 | 110-2 v CádizCádiz 2-0 Rayo Vallecano | Spanish La Liga |
| 17 | Sun 13 Mar 2022 | 111-1 v SevillaRayo Vallecano 1-1 Sevilla | Spanish La Liga |
| 18 | Sat 19 Mar 2022 | 110-1 v Atlético MadridRayo Vallecano 0-1 Atlético Madrid | Spanish La Liga |
| 19 | Sun 3 Apr 2022 | 112-2 v GranadaGranada 2-2 Rayo Vallecano | Spanish La Liga |
| 20 | Mon 11 Apr 2022 | 111-1 v ValenciaRayo Vallecano 1-1 Valencia | Spanish La Liga |
| 21 | Thu 12 May 2022 | 11 1-5 v VillarrealRayo Vallecano 1-5 Villarreal | Spanish La Liga |
| 22 | Sun 15 May 2022 | 111-2 v MallorcaMallorca 2-1 Rayo Vallecano | Spanish La Liga |
| 23 | Fri 20 May 2022 | 112-4 v LevanteRayo Vallecano 2-4 Levante | Spanish La Liga |
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