| 1 | Fri 13 Aug 2021 | 23 1-0 v GetafeValencia 1-0 Getafe | Spanish La Liga |
| 2 | Sat 21 Aug 2021 | 231-1 v GranadaGranada 1-1 Valencia | Spanish La Liga |
| 3 | Wed 22 Sep 2021 | 231-3 v SevillaSevilla 3-1 Valencia | Spanish La Liga |
| 4 | Sat 25 Sep 2021 | 23 1-1 v Athletic BilbaoValencia 1-1 Athletic Bilbao | Spanish La Liga |
| 5 | Sat 23 Oct 2021 | 232-2 v MallorcaValencia 2-2 Mallorca | Spanish La Liga |
| 6 | Sun 9 Jan 2022 | 250-0 v Athletic BilbaoAlavés 0-0 Athletic Bilbao | Spanish La Liga |
| 7 | Tue 18 Jan 2022 | 250-4 v Real BetisReal Betis 4-0 Alavés | Spanish La Liga |
| 8 | Sun 23 Jan 2022 | 250-1 v BarcelonaAlavés 0-1 Barcelona | Spanish La Liga |
| 9 | Sat 5 Feb 2022 | 251-3 v ElcheElche 3-1 Alavés | Spanish La Liga |
| 10 | Sun 13 Feb 2022 | 252-1 v ValenciaAlavés 2-1 Valencia | Spanish La Liga |
| 11 | Sat 19 Feb 2022 | 250-3 v Real MadridReal Madrid 3-0 Alavés | Spanish La Liga |
| 12 | Fri 4 Mar 2022 | 250-0 v SevillaAlavés 0-0 Sevilla | Spanish La Liga |
| 13 | Sun 13 Mar 2022 | 250-1 v Real SociedadReal Sociedad 1-0 Alavés | Spanish La Liga |
| 14 | Sat 19 Mar 2022 | 252-3 v GranadaAlavés 2-3 Granada | Spanish La Liga |
| 15 | Sat 16 Apr 2022 | 251-0 v Rayo VallecanoAlavés 1-0 Rayo Vallecano | Spanish La Liga |
| 16 | Sat 30 Apr 2022 | 25 2-1 v VillarrealAlavés 2-1 Villarreal | Spanish La Liga |
| 17 | Wed 11 May 2022 | 252-1 v EspanyolAlavés 2-1 Espanyol | Spanish La Liga |
| 18 | Sun 15 May 2022 | 251-3 v LevanteLevante 3-1 Alavés | Spanish La Liga |
| 19 | Sun 22 May 2022 | 250-1 v CádizAlavés 0-1 Cádiz | Spanish La Liga |
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