| 1 | Sun 22 Aug 2021 | 240-1 v Real SociedadReal Sociedad 1-0 Rayo Vallecano | Spanish La Liga |
| 2 | Sun 29 Aug 2021 | 244-0 v GranadaRayo Vallecano 4-0 Granada | Spanish La Liga |
| 3 | Sat 11 Sep 2021 | 241-1 v LevanteLevante 1-1 Rayo Vallecano | Spanish La Liga |
| 4 | Sat 18 Sep 2021 | 24 3-0 v GetafeRayo Vallecano 3-0 Getafe | Spanish La Liga |
| 5 | Sun 26 Sep 2021 | 243-1 v CádizRayo Vallecano 3-1 Cádiz | Spanish La Liga |
| 6 | Sat 2 Oct 2021 | 240-1 v OsasunaOsasuna 1-0 Rayo Vallecano | Spanish La Liga |
| 7 | Sun 17 Oct 2021 | 242-1 v ElcheRayo Vallecano 2-1 Elche | Spanish La Liga |
| 8 | Wed 27 Oct 2021 | 24 1-0 v BarcelonaRayo Vallecano 1-0 Barcelona | Spanish La Liga |
| 9 | Sat 6 Nov 2021 | 241-2 v Real MadridReal Madrid 2-1 Rayo Vallecano | Spanish La Liga |
| 10 | Mon 22 Nov 2021 | 243-1 v MallorcaRayo Vallecano 3-1 Mallorca | Spanish La Liga |
| 11 | Sat 27 Nov 2021 | 24 1-1 v ValenciaValencia 1-1 Rayo Vallecano | Spanish La Liga |
| 12 | Sun 5 Dec 2021 | 241-0 v EspanyolRayo Vallecano 1-0 Espanyol | Spanish La Liga |
| 13 | Sun 12 Dec 2021 | 240-2 v VillarrealVillarreal 2-0 Rayo Vallecano | Spanish La Liga |
| 14 | Sat 18 Dec 2021 | 242-0 v AlavésRayo Vallecano 2-0 Alavés | Spanish La Liga |
| 15 | Sun 2 Jan 2022 | 240-2 v Atlético MadridAtlético Madrid 2-0 Rayo Vallecano | Spanish La Liga |
| 16 | Sun 9 Jan 2022 | 241-1 v Real BetisRayo Vallecano 1-1 Real Betis | Spanish La Liga |
| 17 | Sun 23 Jan 2022 | 240-1 v Athletic BilbaoRayo Vallecano 0-1 Athletic Bilbao | Spanish La Liga |
| 18 | Sat 5 Feb 2022 | 240-2 v Celta VigoCelta Vigo 2-0 Rayo Vallecano | Spanish La Liga |
| 19 | Sat 12 Feb 2022 | 24 0-3 v OsasunaRayo Vallecano 0-3 Osasuna | Spanish La Liga |
| 20 | Fri 18 Feb 2022 | 241-2 v ElcheElche 2-1 Rayo Vallecano | Spanish La Liga |
| 21 | Sun 6 Mar 2022 | 240-2 v CádizCádiz 2-0 Rayo Vallecano | Spanish La Liga |
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