| 1 | Tue 2 Aug 2022 | 41-1 v MonacoMonaco 1-1 PSV Eindhoven | UEFA Champions League Third Qualifying Round |
| 2 | Sat 6 Aug 2022 | 44-1 v FC EmmenPSV Eindhoven 4-1 FC Emmen | Dutch Eredivisie |
| 3 | Tue 9 Aug 2022 | 4 3-2 v MonacoPSV Eindhoven 3-2 Monaco | UEFA Champions League Third Qualifying Round |
| 4 | Sat 13 Aug 2022 | 45-2 v Go Ahead EaglesGo Ahead Eagles 2-5 PSV Eindhoven | Dutch Eredivisie |
| 5 | Tue 16 Aug 2022 | 4 2-2 v RangersRangers 2-2 PSV Eindhoven | UEFA Champions League Play-off |
| 6 | Wed 24 Aug 2022 | 4 0-1 v RangersPSV Eindhoven 0-1 Rangers | UEFA Champions League Play-off |
| 7 | Sun 28 Aug 2022 | 46-1 v Excelsior RotterdamExcelsior Rotterdam 1-6 PSV Eindhoven | Dutch Eredivisie |
| 8 | Wed 31 Aug 2022 | 47-1 v VolendamPSV Eindhoven 7-1 Volendam | Dutch Eredivisie |
| 9 | Sat 3 Sep 2022 | 41-2 v FC TwenteFC Twente 2-1 PSV Eindhoven | Dutch Eredivisie |
| 10 | Sun 11 Sep 2022 | 41-0 v RKC WaalwijkPSV Eindhoven 1-0 RKC Waalwijk | Dutch Eredivisie |
| 11 | Sun 18 Sep 2022 | 44-3 v FeyenoordPSV Eindhoven 4-3 Feyenoord | Dutch Eredivisie |
| 12 | Sat 1 Oct 2022 | 40-3 v SC CambuurSC Cambuur 3-0 PSV Eindhoven | Dutch Eredivisie |
| 13 | Thu 6 Oct 2022 | 45-1 v FC ZurichFC Zurich 1-5 PSV Eindhoven | UEFA Europa League Group A |
| 14 | Sun 9 Oct 2022 | 41-0 v sc Heerenveensc Heerenveen 0-1 PSV Eindhoven | Dutch Eredivisie |
| 15 | Thu 13 Oct 2022 | 45-0 v FC ZurichPSV Eindhoven 5-0 FC Zurich | UEFA Europa League Group A |
| 16 | Sun 16 Oct 2022 | 46-1 v FC UtrechtPSV Eindhoven 6-1 FC Utrecht | Dutch Eredivisie |
| 17 | Thu 20 Oct 2022 | 40-1 v ArsenalArsenal 1-0 PSV Eindhoven | UEFA Europa League Group A |
| 18 | Sun 23 Oct 2022 | 42-4 v FC GroningenFC Groningen 4-2 PSV Eindhoven | Dutch Eredivisie |
| 19 | Sun 30 Oct 2022 | 43-0 v NEC NijmegenPSV Eindhoven 3-0 NEC Nijmegen | Dutch Eredivisie |
| 20 | Sun 6 Nov 2022 | 4 2-1 v AjaxAjax 1-2 PSV Eindhoven | Dutch Eredivisie |
| 21 | Sat 12 Nov 2022 | 40-1 v AZ AlkmaarPSV Eindhoven 0-1 AZ Alkmaar | Dutch Eredivisie |
| 22 | Sat 7 Jan 2023 | 40-0 v Sparta RotterdamPSV Eindhoven 0-0 Sparta Rotterdam | Dutch Eredivisie |
| 23 | Sun 15 Jan 2023 | 42-2 v Fortuna SittardFortuna Sittard 2-2 PSV Eindhoven | Dutch Eredivisie |
| 24 | Sat 21 Jan 2023 | 41-0 v VitessePSV Eindhoven 1-0 Vitesse | Dutch Eredivisie |
| 25 | Tue 24 Jan 2023 | 40-1 v FC EmmenFC Emmen 1-0 PSV Eindhoven | Dutch Eredivisie |
| 26 | Sat 28 Jan 2023 | 42-0 v Go Ahead EaglesPSV Eindhoven 2-0 Go Ahead Eagles | Dutch Eredivisie |
| 27 | Sun 5 Feb 2023 | 4 2-2 v FeyenoordFeyenoord 2-2 PSV Eindhoven | Dutch Eredivisie |
| 28 | Thu 16 Feb 2023 | 40-3 v SevillaSevilla 3-0 PSV Eindhoven | UEFA Europa League |
| 29 | Sun 19 Feb 2023 | 42-2 v FC UtrechtFC Utrecht 2-2 PSV Eindhoven | Dutch Eredivisie |
| 30 | Sun 19 Mar 2023 | 41-1 v VitesseVitesse 1-1 PSV Eindhoven | Dutch Eredivisie |
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