| 1 | Tue 2 Aug 2022 | 31-1 v MonacoMonaco 1-1 PSV Eindhoven | UEFA Champions League Third Qualifying Round |
| 2 | Sat 6 Aug 2022 | 34-1 v FC EmmenPSV Eindhoven 4-1 FC Emmen | Dutch Eredivisie |
| 3 | Tue 9 Aug 2022 | 33-2 v MonacoPSV Eindhoven 3-2 Monaco | UEFA Champions League Third Qualifying Round |
| 4 | Sat 13 Aug 2022 | 35-2 v Go Ahead EaglesGo Ahead Eagles 2-5 PSV Eindhoven | Dutch Eredivisie |
| 5 | Tue 16 Aug 2022 | 32-2 v RangersRangers 2-2 PSV Eindhoven | UEFA Champions League Play-off |
| 6 | Wed 24 Aug 2022 | 30-1 v RangersPSV Eindhoven 0-1 Rangers | UEFA Champions League Play-off |
| 7 | Sun 28 Aug 2022 | 36-1 v Excelsior RotterdamExcelsior Rotterdam 1-6 PSV Eindhoven | Dutch Eredivisie |
| 8 | Wed 31 Aug 2022 | 37-1 v VolendamPSV Eindhoven 7-1 Volendam | Dutch Eredivisie |
| 9 | Sat 3 Sep 2022 | 31-2 v FC TwenteFC Twente 2-1 PSV Eindhoven | Dutch Eredivisie |
| 10 | Sun 11 Sep 2022 | 31-0 v RKC WaalwijkPSV Eindhoven 1-0 RKC Waalwijk | Dutch Eredivisie |
| 11 | Sun 18 Sep 2022 | 34-3 v FeyenoordPSV Eindhoven 4-3 Feyenoord | Dutch Eredivisie |
| 12 | Sat 1 Oct 2022 | 30-3 v SC CambuurSC Cambuur 3-0 PSV Eindhoven | Dutch Eredivisie |
| 13 | Thu 6 Oct 2022 | 35-1 v FC ZurichFC Zurich 1-5 PSV Eindhoven | UEFA Europa League Group A |
| 14 | Thu 13 Oct 2022 | 35-0 v FC ZurichPSV Eindhoven 5-0 FC Zurich | UEFA Europa League Group A |
| 15 | Sun 16 Oct 2022 | 36-1 v FC UtrechtPSV Eindhoven 6-1 FC Utrecht | Dutch Eredivisie |
| 16 | Thu 20 Oct 2022 | 30-1 v ArsenalArsenal 1-0 PSV Eindhoven | UEFA Europa League Group A |
| 17 | Sun 23 Oct 2022 | 32-4 v FC GroningenFC Groningen 4-2 PSV Eindhoven | Dutch Eredivisie |
| 18 | Thu 27 Oct 2022 | 32-0 v ArsenalPSV Eindhoven 2-0 Arsenal | UEFA Europa League Group A |
| 19 | Sun 30 Oct 2022 | 33-0 v NEC NijmegenPSV Eindhoven 3-0 NEC Nijmegen | Dutch Eredivisie |
| 20 | Sun 6 Nov 2022 | 32-1 v AjaxAjax 1-2 PSV Eindhoven | Dutch Eredivisie |
| 21 | Sat 7 Jan 2023 | 30-0 v Sparta RotterdamPSV Eindhoven 0-0 Sparta Rotterdam | Dutch Eredivisie |
| 22 | Sun 15 Jan 2023 | 32-2 v Fortuna SittardFortuna Sittard 2-2 PSV Eindhoven | Dutch Eredivisie |
| 23 | Sat 21 Jan 2023 | 31-0 v VitessePSV Eindhoven 1-0 Vitesse | Dutch Eredivisie |
| 24 | Tue 24 Jan 2023 | 3 0-1 v FC EmmenFC Emmen 1-0 PSV Eindhoven | Dutch Eredivisie |
| 25 | Sat 28 Jan 2023 | 32-0 v Go Ahead EaglesPSV Eindhoven 2-0 Go Ahead Eagles | Dutch Eredivisie |
| 26 | Sun 5 Feb 2023 | 32-2 v FeyenoordFeyenoord 2-2 PSV Eindhoven | Dutch Eredivisie |
| 27 | Sat 11 Feb 2023 | 36-0 v FC GroningenPSV Eindhoven 6-0 FC Groningen | Dutch Eredivisie |
| 28 | Thu 16 Feb 2023 | 30-3 v SevillaSevilla 3-0 PSV Eindhoven | UEFA Europa League |
| 29 | Sun 19 Feb 2023 | 32-2 v FC UtrechtFC Utrecht 2-2 PSV Eindhoven | Dutch Eredivisie |
| 30 | Sat 1 Apr 2023 | 34-2 v NEC NijmegenNEC Nijmegen 2-4 PSV Eindhoven | Dutch Eredivisie |
| 31 | Sat 8 Apr 2023 | 34-0 v Excelsior RotterdamPSV Eindhoven 4-0 Excelsior Rotterdam | Dutch Eredivisie |
| 32 | Sun 16 Apr 2023 | 3 3-2 v VolendamVolendam 2-3 PSV Eindhoven | Dutch Eredivisie |
| 33 | Sun 23 Apr 2023 | 33-0 v AjaxPSV Eindhoven 3-0 Ajax | Dutch Eredivisie |
| 34 | Sat 6 May 2023 | 31-0 v Sparta RotterdamSparta Rotterdam 0-1 PSV Eindhoven | Dutch Eredivisie |
| 35 | Sun 14 May 2023 | 32-1 v Fortuna SittardPSV Eindhoven 2-1 Fortuna Sittard | Dutch Eredivisie |
| 36 | Sun 28 May 2023 | 32-1 v AZ AlkmaarAZ Alkmaar 1-2 PSV Eindhoven | Dutch Eredivisie |
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