| 1 | Sat 13 Aug 2022 | 73-0 v Real ValladolidReal Valladolid 0-3 Villarreal | Spanish La Liga |
| 2 | Thu 18 Aug 2022 | 74-2 v Hajduk SplitVillarreal 4-2 Hajduk Split | UEFA Europa Conference League Play-off |
| 3 | Sun 21 Aug 2022 | 7 2-0 v Atlético MadridAtlético Madrid 0-2 Villarreal | Spanish La Liga |
| 4 | Thu 25 Aug 2022 | 7 2-0 v Hajduk SplitHajduk Split 0-2 Villarreal | UEFA Europa Conference League Play-off |
| 5 | Sun 28 Aug 2022 | 70-0 v GetafeGetafe 0-0 Villarreal | Spanish La Liga |
| 6 | Sun 4 Sep 2022 | 74-0 v ElcheVillarreal 4-0 Elche | Spanish La Liga |
| 7 | Thu 8 Sep 2022 | 74-3 v Lech PoznańVillarreal 4-3 Lech Poznań | UEFA Europa Conference League Group C |
| 8 | Sun 11 Sep 2022 | 70-1 v Real BetisReal Betis 1-0 Villarreal | Spanish La Liga |
| 9 | Wed 9 Nov 2022 | 71-0 v EspanyolEspanyol 0-1 Villarreal | Spanish La Liga |
| 10 | Sat 31 Dec 2022 | 72-1 v ValenciaVillarreal 2-1 Valencia | Spanish La Liga |
| 11 | Sat 7 Jan 2023 | 72-1 v Real MadridVillarreal 2-1 Real Madrid | Spanish La Liga |
| 12 | Fri 13 Jan 2023 | 71-1 v Celta VigoCelta Vigo 1-1 Villarreal | Spanish La Liga |
| 13 | Sun 22 Jan 2023 | 7 1-0 v GironaVillarreal 1-0 Girona | Spanish La Liga |
| 14 | Mon 30 Jan 2023 | 70-1 v Rayo VallecanoVillarreal 0-1 Rayo Vallecano | Spanish La Liga |
| 15 | Sat 4 Feb 2023 | 71-3 v ElcheElche 3-1 Villarreal | Spanish La Liga |
| 16 | Mon 27 Feb 2023 | 72-1 v GetafeVillarreal 2-1 Getafe | Spanish La Liga |
| 17 | Sat 4 Mar 2023 | 7 2-0 v AlmeríaAlmería 0-2 Villarreal | Spanish La Liga |
| 18 | Thu 9 Mar 2023 | 71-1 v RSC AnderlechtRSC Anderlecht 1-1 Villarreal | UEFA Europa Conference League Round of 16 |
| 19 | Sun 12 Mar 2023 | 7 1-1 v Real BetisVillarreal 1-1 Real Betis | Spanish La Liga |
| 20 | Thu 16 Mar 2023 | 70-1 v RSC AnderlechtVillarreal 0-1 RSC Anderlecht | UEFA Europa Conference League Round of 16 |
| 21 | Sun 19 Mar 2023 | 73-0 v OsasunaOsasuna 0-3 Villarreal | Spanish La Liga |
| 22 | Wed 3 May 2023 | 71-1 v ValenciaValencia 1-1 Villarreal | Spanish La Liga |
| 23 | Sat 13 May 2023 | 75-1 v Athletic BilbaoVillarreal 5-1 Athletic Bilbao | Spanish La Liga |
| 24 | Sat 20 May 2023 | 72-1 v GironaGirona 1-2 Villarreal | Spanish La Liga |
| 25 | Wed 24 May 2023 | 72-0 v CádizVillarreal 2-0 Cádiz | Spanish La Liga |
| 26 | Sun 28 May 2023 | 71-2 v Rayo VallecanoRayo Vallecano 2-1 Villarreal | Spanish La Liga |
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