| 1 | Sat 13 Aug 2022 | 43-0 v Real ValladolidReal Valladolid 0-3 Villarreal | Spanish La Liga |
| 2 | Thu 18 Aug 2022 | 44-2 v Hajduk SplitVillarreal 4-2 Hajduk Split | UEFA Europa Conference League Play-off |
| 3 | Sun 21 Aug 2022 | 42-0 v Atlético MadridAtlético Madrid 0-2 Villarreal | Spanish La Liga |
| 4 | Thu 25 Aug 2022 | 42-0 v Hajduk SplitHajduk Split 0-2 Villarreal | UEFA Europa Conference League Play-off |
| 5 | Sun 28 Aug 2022 | 4 0-0 v GetafeGetafe 0-0 Villarreal | Spanish La Liga |
| 6 | Sun 4 Sep 2022 | 44-0 v ElcheVillarreal 4-0 Elche | Spanish La Liga |
| 7 | Sun 11 Sep 2022 | 40-1 v Real BetisReal Betis 1-0 Villarreal | Spanish La Liga |
| 8 | Sun 18 Sep 2022 | 41-1 v SevillaVillarreal 1-1 Sevilla | Spanish La Liga |
| 9 | Sat 24 Sep 2022 | 41-2 v SwitzerlandSpain 1-2 Switzerland | UEFA Nations League League A Group 2 |
| 10 | Tue 27 Sep 2022 | 41-0 v PortugalPortugal 0-1 Spain | UEFA Nations League League A Group 2 |
| 11 | Sat 1 Oct 2022 | 40-0 v CádizCádiz 0-0 Villarreal | Spanish La Liga |
| 12 | Sun 9 Oct 2022 | 4 0-1 v Real SociedadReal Sociedad 1-0 Villarreal | Spanish La Liga |
| 13 | Thu 13 Oct 2022 | 41-0 v Austria ViennaAustria Vienna 0-1 Villarreal | UEFA Europa Conference League Group C |
| 14 | Mon 17 Oct 2022 | 42-0 v OsasunaVillarreal 2-0 Osasuna | Spanish La Liga |
| 15 | Thu 20 Oct 2022 | 4 0-3 v BarcelonaBarcelona 3-0 Villarreal | Spanish La Liga |
| 16 | Sun 23 Oct 2022 | 4 2-1 v AlmeríaVillarreal 2-1 Almería | Spanish La Liga |
| 17 | Sun 30 Oct 2022 | 40-1 v Athletic BilbaoAthletic Bilbao 1-0 Villarreal | Spanish La Liga |
| 18 | Sun 6 Nov 2022 | 4 0-2 v MallorcaVillarreal 0-2 Mallorca | Spanish La Liga |
| 19 | Thu 17 Nov 2022 | 43-1 v JordanJordan 1-3 Spain | International Friendly |
| 20 | Thu 1 Dec 2022 | 41-2 v JapanJapan 2-1 Spain | World Cup Group E |
| 21 | Sat 31 Dec 2022 | 42-1 v ValenciaVillarreal 2-1 Valencia | Spanish La Liga |
| 22 | Sat 7 Jan 2023 | 4 2-1 v Real MadridVillarreal 2-1 Real Madrid | Spanish La Liga |
| 23 | Fri 13 Jan 2023 | 41-1 v Celta VigoCelta Vigo 1-1 Villarreal | Spanish La Liga |
| 24 | Sun 22 Jan 2023 | 4 1-0 v GironaVillarreal 1-0 Girona | Spanish La Liga |
| 25 | Sun 12 Feb 2023 | 4 0-1 v BarcelonaVillarreal 0-1 Barcelona | Spanish La Liga |
| 26 | Sat 18 Feb 2023 | 42-4 v MallorcaMallorca 4-2 Villarreal | Spanish La Liga |
| 27 | Mon 27 Feb 2023 | 42-1 v GetafeVillarreal 2-1 Getafe | Spanish La Liga |
| 28 | Sat 4 Mar 2023 | 42-0 v AlmeríaAlmería 0-2 Villarreal | Spanish La Liga |
| 29 | Sun 12 Mar 2023 | 4 1-1 v Real BetisVillarreal 1-1 Real Betis | Spanish La Liga |
| 30 | Sun 19 Mar 2023 | 43-0 v OsasunaOsasuna 0-3 Villarreal | Spanish La Liga |
| 31 | Sun 2 Apr 2023 | 42-0 v Real SociedadVillarreal 2-0 Real Sociedad | Spanish La Liga |
| 32 | Sat 8 Apr 2023 | 43-2 v Real MadridReal Madrid 2-3 Villarreal | Spanish La Liga |
| 33 | Sat 15 Apr 2023 | 41-2 v Real ValladolidVillarreal 1-2 Real Valladolid | Spanish La Liga |
| 34 | Sun 23 Apr 2023 | 41-2 v SevillaSevilla 2-1 Villarreal | Spanish La Liga |
| 35 | Thu 27 Apr 2023 | 44-2 v EspanyolVillarreal 4-2 Espanyol | Spanish La Liga |
| 36 | Sun 30 Apr 2023 | 43-1 v Celta VigoVillarreal 3-1 Celta Vigo | Spanish La Liga |
| 37 | Wed 3 May 2023 | 41-1 v ValenciaValencia 1-1 Villarreal | Spanish La Liga |
| 38 | Sat 13 May 2023 | 4 5-1 v Athletic BilbaoVillarreal 5-1 Athletic Bilbao | Spanish La Liga |
| 39 | Wed 24 May 2023 | 42-0 v CádizVillarreal 2-0 Cádiz | Spanish La Liga |
| 40 | Sun 28 May 2023 | 41-2 v Rayo VallecanoRayo Vallecano 2-1 Villarreal | Spanish La Liga |
| 41 | Sun 4 Jun 2023 | 42-2 v Atlético MadridVillarreal 2-2 Atlético Madrid | Spanish La Liga |
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