| 1 | Sat 13 Aug 2022 | 100-3 v VillarrealReal Valladolid 0-3 Villarreal | Spanish La Liga |
| 2 | Fri 19 Aug 2022 | 101-1 v SevillaSevilla 1-1 Real Valladolid | Spanish La Liga |
| 3 | Sun 28 Aug 2022 | 100-4 v BarcelonaBarcelona 4-0 Real Valladolid | Spanish La Liga |
| 4 | Mon 5 Sep 2022 | 101-0 v AlmeríaReal Valladolid 1-0 Almería | Spanish La Liga |
| 5 | Fri 9 Sep 2022 | 101-2 v GironaGirona 2-1 Real Valladolid | Spanish La Liga |
| 6 | Fri 16 Sep 2022 | 100-1 v CádizReal Valladolid 0-1 Cádiz | Spanish La Liga |
| 7 | Sat 1 Oct 2022 | 103-2 v GetafeGetafe 2-3 Real Valladolid | Spanish La Liga |
| 8 | Sun 9 Oct 2022 | 100-0 v Real BetisReal Valladolid 0-0 Real Betis | Spanish La Liga |
| 9 | Sun 16 Oct 2022 | 100-1 v EspanyolEspanyol 1-0 Real Valladolid | Spanish La Liga |
| 10 | Wed 19 Oct 2022 | 104-1 v Celta VigoReal Valladolid 4-1 Celta Vigo | Spanish La Liga |
| 11 | Sat 22 Oct 2022 | 10 1-0 v Real SociedadReal Valladolid 1-0 Real Sociedad | Spanish La Liga |
| 12 | Sun 30 Oct 2022 | 100-2 v OsasunaOsasuna 2-0 Real Valladolid | Spanish La Liga |
| 13 | Sat 5 Nov 2022 | 102-1 v ElcheReal Valladolid 2-1 Elche | Spanish La Liga |
| 14 | Tue 8 Nov 2022 | 100-3 v Athletic BilbaoAthletic Bilbao 3-0 Real Valladolid | Spanish La Liga |
| 15 | Fri 30 Dec 2022 | 100-2 v Real MadridReal Valladolid 0-2 Real Madrid | Spanish La Liga |
| 16 | Sat 7 Jan 2023 | 100-1 v MallorcaMallorca 1-0 Real Valladolid | Spanish La Liga |
| 17 | Sat 14 Jan 2023 | 100-1 v Rayo VallecanoReal Valladolid 0-1 Rayo Vallecano | Spanish La Liga |
| 18 | Sat 21 Jan 2023 | 100-3 v Atlético MadridAtlético Madrid 3-0 Real Valladolid | Spanish La Liga |
| 19 | Sun 29 Jan 2023 | 101-0 v ValenciaReal Valladolid 1-0 Valencia | Spanish La Liga |
| 20 | Sun 5 Feb 2023 | 10 1-0 v Real SociedadReal Sociedad 0-1 Real Valladolid | Spanish La Liga |
| 21 | Sun 12 Feb 2023 | 100-0 v OsasunaReal Valladolid 0-0 Osasuna | Spanish La Liga |
| 22 | Sat 18 Feb 2023 | 101-2 v Real BetisReal Betis 2-1 Real Valladolid | Spanish La Liga |
| 23 | Sun 26 Feb 2023 | 100-3 v Celta VigoCelta Vigo 3-0 Real Valladolid | Spanish La Liga |
| 24 | Sun 5 Mar 2023 | 102-1 v EspanyolReal Valladolid 2-1 Espanyol | Spanish La Liga |
| 25 | Sat 11 Mar 2023 | 10 1-1 v ElcheElche 1-1 Real Valladolid | Spanish La Liga |
| 26 | Fri 17 Mar 2023 | 101-3 v Athletic BilbaoReal Valladolid 1-3 Athletic Bilbao | Spanish La Liga |
| 27 | Sun 2 Apr 2023 | 100-6 v Real MadridReal Madrid 6-0 Real Valladolid | Spanish La Liga |
| 28 | Sun 9 Apr 2023 | 103-3 v MallorcaReal Valladolid 3-3 Mallorca | Spanish La Liga |
| 29 | Thu 27 Apr 2023 | 101-2 v ValenciaValencia 2-1 Real Valladolid | Spanish La Liga |
| 30 | Sun 30 Apr 2023 | 102-5 v Atlético MadridReal Valladolid 2-5 Atlético Madrid | Spanish La Liga |
| 31 | Sun 14 May 2023 | 100-3 v SevillaReal Valladolid 0-3 Sevilla | Spanish La Liga |
| 32 | Tue 23 May 2023 | 103-1 v BarcelonaReal Valladolid 3-1 Barcelona | Spanish La Liga |
| 33 | Sun 28 May 2023 | 100-0 v AlmeríaAlmería 0-0 Real Valladolid | Spanish La Liga |
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