| 1 | Thu 18 Aug 2022 | 24-2 v Hajduk SplitVillarreal 4-2 Hajduk Split | UEFA Europa Conference League Play-off |
| 2 | Thu 25 Aug 2022 | 22-0 v Hajduk SplitHajduk Split 0-2 Villarreal | UEFA Europa Conference League Play-off |
| 3 | Sun 28 Aug 2022 | 20-0 v GetafeGetafe 0-0 Villarreal | Spanish La Liga |
| 4 | Sun 4 Sep 2022 | 24-0 v ElcheVillarreal 4-0 Elche | Spanish La Liga |
| 5 | Thu 8 Sep 2022 | 24-3 v Lech PoznańVillarreal 4-3 Lech Poznań | UEFA Europa Conference League Group C |
| 6 | Sun 11 Sep 2022 | 20-1 v Real BetisReal Betis 1-0 Villarreal | Spanish La Liga |
| 7 | Thu 15 Sep 2022 | 22-1 v Hapoel Be-er ShevaHapoel Be-er Sheva 1-2 Villarreal | UEFA Europa Conference League Group C |
| 8 | Sun 18 Sep 2022 | 21-1 v SevillaVillarreal 1-1 Sevilla | Spanish La Liga |
| 9 | Sat 1 Oct 2022 | 20-0 v CádizCádiz 0-0 Villarreal | Spanish La Liga |
| 10 | Sun 9 Oct 2022 | 20-1 v Real SociedadReal Sociedad 1-0 Villarreal | Spanish La Liga |
| 11 | Thu 20 Oct 2022 | 20-3 v BarcelonaBarcelona 3-0 Villarreal | Spanish La Liga |
| 12 | Sun 23 Oct 2022 | 22-1 v AlmeríaVillarreal 2-1 Almería | Spanish La Liga |
| 13 | Thu 27 Oct 2022 | 22-2 v Hapoel Be-er ShevaVillarreal 2-2 Hapoel Be-er Sheva | UEFA Europa Conference League Group C |
| 14 | Sun 30 Oct 2022 | 20-1 v Athletic BilbaoAthletic Bilbao 1-0 Villarreal | Spanish La Liga |
| 15 | Thu 3 Nov 2022 | 20-3 v Lech PoznańLech Poznań 3-0 Villarreal | UEFA Europa Conference League Group C |
| 16 | Sun 6 Nov 2022 | 20-2 v MallorcaVillarreal 0-2 Mallorca | Spanish La Liga |
| 17 | Wed 9 Nov 2022 | 21-0 v EspanyolEspanyol 0-1 Villarreal | Spanish La Liga |
| 18 | Sat 31 Dec 2022 | 22-1 v ValenciaVillarreal 2-1 Valencia | Spanish La Liga |
| 19 | Fri 13 Jan 2023 | 21-1 v Celta VigoCelta Vigo 1-1 Villarreal | Spanish La Liga |
| 20 | Mon 30 Jan 2023 | 20-1 v Rayo VallecanoVillarreal 0-1 Rayo Vallecano | Spanish La Liga |
| 21 | Sun 19 Mar 2023 | 23-0 v OsasunaOsasuna 0-3 Villarreal | Spanish La Liga |
| 22 | Sat 8 Apr 2023 | 23-2 v Real MadridReal Madrid 2-3 Villarreal | Spanish La Liga |
| 23 | Sat 15 Apr 2023 | 21-2 v Real ValladolidVillarreal 1-2 Real Valladolid | Spanish La Liga |
| 24 | Sat 20 May 2023 | 22-1 v GironaGirona 1-2 Villarreal | Spanish La Liga |
| 25 | Wed 24 May 2023 | 22-0 v CádizVillarreal 2-0 Cádiz | Spanish La Liga |
| 26 | Sun 4 Jun 2023 | 22-2 v Atlético MadridVillarreal 2-2 Atlético Madrid | Spanish La Liga |
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