| 1 | Thu 18 Aug 2022 | 174-2 v Hajduk SplitVillarreal 4-2 Hajduk Split | UEFA Europa Conference League Play-off |
| 2 | Sun 21 Aug 2022 | 172-0 v Atlético MadridAtlético Madrid 0-2 Villarreal | Spanish La Liga |
| 3 | Thu 25 Aug 2022 | 172-0 v Hajduk SplitHajduk Split 0-2 Villarreal | UEFA Europa Conference League Play-off |
| 4 | Sun 28 Aug 2022 | 170-0 v GetafeGetafe 0-0 Villarreal | Spanish La Liga |
| 5 | Sun 4 Sep 2022 | 174-0 v ElcheVillarreal 4-0 Elche | Spanish La Liga |
| 6 | Sun 11 Sep 2022 | 170-1 v Real BetisReal Betis 1-0 Villarreal | Spanish La Liga |
| 7 | Sun 18 Sep 2022 | 171-1 v SevillaVillarreal 1-1 Sevilla | Spanish La Liga |
| 8 | Sat 24 Sep 2022 | 203-0 v HondurasArgentina 3-0 Honduras | International Friendly |
| 9 | Wed 28 Sep 2022 | 203-0 v JamaicaArgentina 3-0 Jamaica | International Friendly |
| 10 | Sat 1 Oct 2022 | 170-0 v CádizCádiz 0-0 Villarreal | Spanish La Liga |
| 11 | Thu 6 Oct 2022 | 175-0 v Austria ViennaVillarreal 5-0 Austria Vienna | UEFA Europa Conference League Group C |
| 12 | Sun 9 Oct 2022 | 17 0-1 v Real SociedadReal Sociedad 1-0 Villarreal | Spanish La Liga |
| 13 | Thu 13 Oct 2022 | 17 1-0 v Austria ViennaAustria Vienna 0-1 Villarreal | UEFA Europa Conference League Group C |
| 14 | Thu 27 Oct 2022 | 172-2 v Hapoel Be-er ShevaVillarreal 2-2 Hapoel Be-er Sheva | UEFA Europa Conference League Group C |
| 15 | Sun 30 Oct 2022 | 170-1 v Athletic BilbaoAthletic Bilbao 1-0 Villarreal | Spanish La Liga |
| 16 | Sat 4 Mar 2023 | 17 2-0 v AlmeríaAlmería 0-2 Villarreal | Spanish La Liga |
| 17 | Thu 9 Mar 2023 | 171-1 v RSC AnderlechtRSC Anderlecht 1-1 Villarreal | UEFA Europa Conference League Round of 16 |
| 18 | Sun 12 Mar 2023 | 171-1 v Real BetisVillarreal 1-1 Real Betis | Spanish La Liga |
| 19 | Thu 16 Mar 2023 | 170-1 v RSC AnderlechtVillarreal 0-1 RSC Anderlecht | UEFA Europa Conference League Round of 16 |
| 20 | Sun 19 Mar 2023 | 173-0 v OsasunaOsasuna 0-3 Villarreal | Spanish La Liga |
| 21 | Sun 2 Apr 2023 | 172-0 v Real SociedadVillarreal 2-0 Real Sociedad | Spanish La Liga |
| 22 | Sat 8 Apr 2023 | 173-2 v Real MadridReal Madrid 2-3 Villarreal | Spanish La Liga |
| 23 | Sat 15 Apr 2023 | 171-2 v Real ValladolidVillarreal 1-2 Real Valladolid | Spanish La Liga |
| 24 | Sun 23 Apr 2023 | 171-2 v SevillaSevilla 2-1 Villarreal | Spanish La Liga |
| 25 | Thu 27 Apr 2023 | 174-2 v EspanyolVillarreal 4-2 Espanyol | Spanish La Liga |
| 26 | Sun 30 Apr 2023 | 173-1 v Celta VigoVillarreal 3-1 Celta Vigo | Spanish La Liga |
| 27 | Sat 13 May 2023 | 175-1 v Athletic BilbaoVillarreal 5-1 Athletic Bilbao | Spanish La Liga |
| 28 | Sat 20 May 2023 | 172-1 v GironaGirona 1-2 Villarreal | Spanish La Liga |
| 29 | Wed 24 May 2023 | 172-0 v CádizVillarreal 2-0 Cádiz | Spanish La Liga |
| 30 | Sun 28 May 2023 | 17 1-2 v Rayo VallecanoRayo Vallecano 2-1 Villarreal | Spanish La Liga |
| 31 | Sun 4 Jun 2023 | 172-2 v Atlético MadridVillarreal 2-2 Atlético Madrid | Spanish La Liga |
| 32 | Thu 15 Jun 2023 | 212-0 v AustraliaArgentina 2-0 Australia | International Friendly |
| 33 | Mon 19 Jun 2023 | 212-0 v IndonesiaIndonesia 0-2 Argentina | International Friendly |
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