| 1 | Thu 8 Sep 2022 | 144-3 v Lech PoznańVillarreal 4-3 Lech Poznań | UEFA Europa Conference League Group C |
| 2 | Mon 17 Oct 2022 | 14 2-0 v OsasunaVillarreal 2-0 Osasuna | Spanish La Liga |
| 3 | Thu 20 Oct 2022 | 140-3 v BarcelonaBarcelona 3-0 Villarreal | Spanish La Liga |
| 4 | Sun 23 Oct 2022 | 142-1 v AlmeríaVillarreal 2-1 Almería | Spanish La Liga |
| 5 | Thu 27 Oct 2022 | 142-2 v Hapoel Be-er ShevaVillarreal 2-2 Hapoel Be-er Sheva | UEFA Europa Conference League Group C |
| 6 | Sun 30 Oct 2022 | 140-1 v Athletic BilbaoAthletic Bilbao 1-0 Villarreal | Spanish La Liga |
| 7 | Thu 3 Nov 2022 | 14 0-3 v Lech PoznańLech Poznań 3-0 Villarreal | UEFA Europa Conference League Group C |
| 8 | Sun 6 Nov 2022 | 140-2 v MallorcaVillarreal 0-2 Mallorca | Spanish La Liga |
| 9 | Wed 9 Nov 2022 | 141-0 v EspanyolEspanyol 0-1 Villarreal | Spanish La Liga |
| 10 | Sat 31 Dec 2022 | 142-1 v ValenciaVillarreal 2-1 Valencia | Spanish La Liga |
| 11 | Sat 7 Jan 2023 | 142-1 v Real MadridVillarreal 2-1 Real Madrid | Spanish La Liga |
| 12 | Fri 13 Jan 2023 | 14 1-1 v Celta VigoCelta Vigo 1-1 Villarreal | Spanish La Liga |
| 13 | Sun 22 Jan 2023 | 141-0 v GironaVillarreal 1-0 Girona | Spanish La Liga |
| 14 | Sat 4 Feb 2023 | 141-3 v ElcheElche 3-1 Villarreal | Spanish La Liga |
| 15 | Sun 12 Feb 2023 | 140-1 v BarcelonaVillarreal 0-1 Barcelona | Spanish La Liga |
| 16 | Sat 18 Feb 2023 | 14 2-4 v MallorcaMallorca 4-2 Villarreal | Spanish La Liga |
| 17 | Thu 9 Mar 2023 | 14 1-1 v RSC AnderlechtRSC Anderlecht 1-1 Villarreal | UEFA Europa Conference League Round of 16 |
| 18 | Sun 12 Mar 2023 | 141-1 v Real BetisVillarreal 1-1 Real Betis | Spanish La Liga |
| 19 | Sun 19 Mar 2023 | 143-0 v OsasunaOsasuna 0-3 Villarreal | Spanish La Liga |
| 20 | Sun 2 Apr 2023 | 142-0 v Real SociedadVillarreal 2-0 Real Sociedad | Spanish La Liga |
| 21 | Sat 8 Apr 2023 | 143-2 v Real MadridReal Madrid 2-3 Villarreal | Spanish La Liga |
| 22 | Sun 30 Apr 2023 | 143-1 v Celta VigoVillarreal 3-1 Celta Vigo | Spanish La Liga |
| 23 | Wed 3 May 2023 | 141-1 v ValenciaValencia 1-1 Villarreal | Spanish La Liga |
| 24 | Sat 13 May 2023 | 145-1 v Athletic BilbaoVillarreal 5-1 Athletic Bilbao | Spanish La Liga |
| 25 | Sat 20 May 2023 | 142-1 v GironaGirona 1-2 Villarreal | Spanish La Liga |
| 26 | Wed 24 May 2023 | 142-0 v CádizVillarreal 2-0 Cádiz | Spanish La Liga |
| 27 | Sun 4 Jun 2023 | 142-2 v Atlético MadridVillarreal 2-2 Atlético Madrid | Spanish La Liga |
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