| 1 | Sat 27 Jul 2013 | 21-2 v Yeovil TownPlymouth Argyle 1-2 Yeovil Town | Friendly |
| 2 | Sat 3 Aug 2013 | 20-1 v Southend UnitedSouthend United 1-0 Plymouth Argyle | Sky Bet League Two |
| 3 | Tue 6 Aug 2013 | 22-3 v Birmingham CityBirmingham City 3-2 Plymouth Argyle | Capital One Cup First Round |
| 4 | Sat 10 Aug 2013 | 20-2 v Fleetwood TownPlymouth Argyle 0-2 Fleetwood Town | Sky Bet League Two |
| 5 | Sat 17 Aug 2013 | 23-1 v Cheltenham TownCheltenham Town 1-3 Plymouth Argyle | Sky Bet League Two |
| 6 | Sat 24 Aug 2013 | 21-0 v RochdalePlymouth Argyle 1-0 Rochdale | Sky Bet League Two |
| 7 | Sat 31 Aug 2013 | 21-2 v MorecambeMorecambe 2-1 Plymouth Argyle | Sky Bet League Two |
| 8 | Sat 7 Sep 2013 | 21-0 v Bristol RoversPlymouth Argyle 1-0 Bristol Rovers | Sky Bet League Two |
| 9 | Sat 14 Sep 2013 | 20-3 v Wycombe WanderersPlymouth Argyle 0-3 Wycombe Wanderers | Sky Bet League Two |
| 10 | Sat 21 Sep 2013 | 20-1 v Scunthorpe UnitedScunthorpe United 1-0 Plymouth Argyle | Sky Bet League Two |
| 11 | Tue 8 Oct 2013 | 21-2 v Swindon TownSwindon Town 2-1 Plymouth Argyle | Johnstone's Paint Trophy Southern Area Second Round |
| 12 | Sat 12 Oct 2013 | 21-1 v PortsmouthPlymouth Argyle 1-1 Portsmouth | Sky Bet League Two |
| 13 | Sat 19 Oct 2013 | 20-1 v Hartlepool UnitedHartlepool United 1-0 Plymouth Argyle | Sky Bet League Two |
| 14 | Sat 26 Oct 2013 | 21-0 v Mansfield TownMansfield Town 0-1 Plymouth Argyle | Sky Bet League Two |
| 15 | Sat 2 Nov 2013 | 21-0 v Northampton TownPlymouth Argyle 1-0 Northampton Town | Sky Bet League Two |
| 16 | Sat 9 Nov 2013 | 20-0 v Lincoln CityLincoln City 0-0 Plymouth Argyle | FA Cup with Budweiser First Round |
| 17 | Sat 16 Nov 2013 | 21-1 v York CityYork City 1-1 Plymouth Argyle | Sky Bet League Two |
| 18 | Wed 20 Nov 2013 | 25-0 v Lincoln CityPlymouth Argyle 5-0 Lincoln City | FA Cup with Budweiser First Round |
| 19 | Sat 23 Nov 2013 | 22-1 v Dagenham & RedbridgePlymouth Argyle 2-1 Dagenham & Redbridge | Sky Bet League Two |
| 20 | Tue 26 Nov 2013 | 21-1 v Torquay UnitedTorquay United 1-1 Plymouth Argyle | Sky Bet League Two |
| 21 | Sat 7 Dec 2013 | 23-1 v Welling UnitedPlymouth Argyle 3-1 Welling United | FA Cup with Budweiser Second Round |
| 22 | Sat 14 Dec 2013 | 20-2 v ChesterfieldChesterfield 2-0 Plymouth Argyle | Sky Bet League Two |
| 23 | Sat 21 Dec 2013 | 22-1 v BuryPlymouth Argyle 2-1 Bury | Sky Bet League Two |
| 24 | Sun 29 Dec 2013 | 21-1 v AFC WimbledonAFC Wimbledon 1-1 Plymouth Argyle | Sky Bet League Two |
| 25 | Sun 5 Jan 2014 | 22-2 v Port ValePort Vale 2-2 Plymouth Argyle | FA Cup with Budweiser Third Round |
| 26 | Tue 14 Jan 2014 | 22-3 v Port ValePlymouth Argyle 2-3 Port Vale | FA Cup with Budweiser Third Round Replay |
| 27 | Sat 15 Feb 2014 | 20-4 v York CityPlymouth Argyle 0-4 York City | Sky Bet League Two |
| 28 | Sat 22 Feb 2014 | 22-1 v Dagenham & RedbridgeDagenham & Redbridge 1-2 Plymouth Argyle | Sky Bet League Two |
| 29 | Tue 25 Feb 2014 | 24-0 v Fleetwood TownFleetwood Town 0-4 Plymouth Argyle | Sky Bet League Two |
| 30 | Sat 1 Mar 2014 | 25-0 v MorecambePlymouth Argyle 5-0 Morecambe | Sky Bet League Two |
| 31 | Sat 8 Mar 2014 | 21-2 v Bristol RoversBristol Rovers 2-1 Plymouth Argyle | Sky Bet League Two |
| 32 | Tue 11 Mar 2014 | 21-0 v Wycombe WanderersWycombe Wanderers 0-1 Plymouth Argyle | Sky Bet League Two |
| 33 | Sat 15 Mar 2014 | 20-2 v Scunthorpe UnitedPlymouth Argyle 0-2 Scunthorpe United | Sky Bet League Two |
| 34 | Tue 25 Mar 2014 | 21-2 v Exeter CityPlymouth Argyle 1-2 Exeter City | Sky Bet League Two |
| 35 | Sat 5 Apr 2014 | 20-1 v Burton AlbionBurton Albion 1-0 Plymouth Argyle | Sky Bet League Two |
| 36 | Tue 8 Apr 2014 | 22-1 v Newport CountyNewport County 1-2 Plymouth Argyle | Sky Bet League Two |
| 37 | Sat 12 Apr 2014 | 20-2 v Oxford UnitedPlymouth Argyle 0-2 Oxford United | Sky Bet League Two |
| 38 | Fri 18 Apr 2014 | 20-4 v BuryBury 4-0 Plymouth Argyle | Sky Bet League Two |
| 39 | Sat 26 Apr 2014 | 21-1 v Hartlepool UnitedPlymouth Argyle 1-1 Hartlepool United | Sky Bet League Two |
| 40 | Sat 3 May 2014 | 23-3 v PortsmouthPortsmouth 3-3 Plymouth Argyle | Sky Bet League Two |
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