| 1 | Sun 8 Aug 2021 | 111-0 v Vitória GuimarãesVitória Guimarães 0-1 Portimonense |
| 2 | Sun 15 Aug 2021 | 11 0-1 v Gil VicentePortimonense 0-1 Gil Vicente |
| 3 | Sun 22 Aug 2021 | 113-0 v TondelaTondela 0-3 Portimonense |
| 4 | Sun 29 Aug 2021 | 110-1 v Paços de FerreiraPortimonense 0-1 Paços de Ferreira |
| 5 | Sun 12 Sep 2021 | 111-1 v BoavistaBoavista 1-1 Portimonense |
| 6 | Fri 17 Sep 2021 | 112-1 v Santa ClaraPortimonense 2-1 Santa Clara |
| 7 | Sun 26 Sep 2021 | 110-0 v VizelaPortimonense 0-0 Vizela |
| 8 | Sun 24 Oct 2021 | 110-2 v Estoril PraiaPortimonense 0-2 Estoril Praia |
| 9 | Sat 27 Nov 2021 | 113-0 v FamalicãoFamalicão 0-3 Portimonense |
| 10 | Sun 12 Dec 2021 | 111-0 v MoreirenseMoreirense 0-1 Portimonense |
| 11 | Sat 18 Dec 2021 | 111-1 v AroucaPortimonense 1-1 Arouca |
| 12 | Wed 29 Dec 2021 | 112-3 v Sporting LisbonSporting Lisbon 3-2 Portimonense |
| 13 | Sun 9 Jan 2022 | 111-2 v MarítimoPortimonense 1-2 Marítimo |
| 14 | Mon 17 Jan 2022 | 11 1-1 v Vitória GuimarãesPortimonense 1-1 Vitória Guimarães |
| 15 | Sun 23 Jan 2022 | 110-1 v Gil VicenteGil Vicente 1-0 Portimonense |
| 16 | Sun 30 Jan 2022 | 111-2 v TondelaPortimonense 1-2 Tondela |
| 17 | Sat 5 Feb 2022 | 111-1 v Paços de FerreiraPaços de Ferreira 1-1 Portimonense |
| 18 | Sat 12 Feb 2022 | 111-1 v BoavistaPortimonense 1-1 Boavista |
| 19 | Mon 21 Feb 2022 | 111-1 v Santa ClaraSanta Clara 1-1 Portimonense |
| 20 | Sat 5 Mar 2022 | 111-2 v BenficaPortimonense 1-2 Benfica |
| 21 | Sat 12 Mar 2022 | 110-2 v Estoril PraiaEstoril Praia 2-0 Portimonense |
| 22 | Sat 16 Apr 2022 | 110-7 v FC PortoFC Porto 7-0 Portimonense |
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