| 1 | Sun 8 Aug 2021 | 941-0 v Vitória GuimarãesVitória Guimarães 0-1 Portimonense |
| 2 | Sun 15 Aug 2021 | 940-1 v Gil VicentePortimonense 0-1 Gil Vicente |
| 3 | Sun 22 Aug 2021 | 94 3-0 v TondelaTondela 0-3 Portimonense |
| 4 | Sun 29 Aug 2021 | 940-1 v Paços de FerreiraPortimonense 0-1 Paços de Ferreira |
| 5 | Sun 12 Sep 2021 | 941-1 v BoavistaBoavista 1-1 Portimonense |
| 6 | Fri 17 Sep 2021 | 942-1 v Santa ClaraPortimonense 2-1 Santa Clara |
| 7 | Sun 26 Sep 2021 | 940-0 v VizelaPortimonense 0-0 Vizela |
| 8 | Sun 3 Oct 2021 | 94 1-0 v BenficaBenfica 0-1 Portimonense |
| 9 | Sun 24 Oct 2021 | 940-2 v Estoril PraiaPortimonense 0-2 Estoril Praia |
| 10 | Mon 1 Nov 2021 | 940-3 v Sporting BragaSporting Braga 3-0 Portimonense |
| 11 | Sat 6 Nov 2021 | 94 2-0 v BelenensesPortimonense 2-0 Belenenses |
| 12 | Sat 27 Nov 2021 | 943-0 v FamalicãoFamalicão 0-3 Portimonense |
| 13 | Fri 3 Dec 2021 | 94 0-3 v FC PortoPortimonense 0-3 FC Porto |
| 14 | Sun 12 Dec 2021 | 941-0 v MoreirenseMoreirense 0-1 Portimonense |
| 15 | Sat 18 Dec 2021 | 941-1 v AroucaPortimonense 1-1 Arouca |
| 16 | Wed 29 Dec 2021 | 942-3 v Sporting LisbonSporting Lisbon 3-2 Portimonense |
| 17 | Sun 9 Jan 2022 | 941-2 v MarítimoPortimonense 1-2 Marítimo |
| 18 | Mon 17 Jan 2022 | 941-1 v Vitória GuimarãesPortimonense 1-1 Vitória Guimarães |
| 19 | Sun 23 Jan 2022 | 940-1 v Gil VicenteGil Vicente 1-0 Portimonense |
| 20 | Sat 5 Feb 2022 | 941-1 v Paços de FerreiraPaços de Ferreira 1-1 Portimonense |
| 21 | Sat 12 Feb 2022 | 941-1 v BoavistaPortimonense 1-1 Boavista |
| 22 | Mon 21 Feb 2022 | 941-1 v Santa ClaraSanta Clara 1-1 Portimonense |
| 23 | Sun 27 Feb 2022 | 941-1 v VizelaVizela 1-1 Portimonense |
| 24 | Sat 5 Mar 2022 | 941-2 v BenficaPortimonense 1-2 Benfica |
| 25 | Sat 12 Mar 2022 | 940-2 v Estoril PraiaEstoril Praia 2-0 Portimonense |
| 26 | Sun 20 Mar 2022 | 941-2 v Sporting BragaPortimonense 1-2 Sporting Braga |
| 27 | Sat 2 Apr 2022 | 940-2 v BelenensesBelenenses 2-0 Portimonense |
| 28 | Sun 10 Apr 2022 | 941-0 v FamalicãoPortimonense 1-0 Famalicão |
| 29 | Sat 23 Apr 2022 | 94 1-0 v MoreirensePortimonense 1-0 Moreirense |
| 30 | Sat 7 May 2022 | 942-3 v Sporting LisbonPortimonense 2-3 Sporting Lisbon |
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