| 1 | Sat 5 Oct | 42-1 v Sparta RotterdamPSV Eindhoven 2-1 Sparta Rotterdam | Dutch Eredivisie |
| 2 | Sat 19 Oct | 42-1 v AZ AlkmaarAZ Alkmaar 1-2 PSV Eindhoven | Dutch Eredivisie |
| 3 | Sat 26 Oct | 46-0 v PEC ZwollePSV Eindhoven 6-0 PEC Zwolle | Dutch Eredivisie |
| 4 | Sat 2 Nov | 42-3 v AjaxAjax 3-2 PSV Eindhoven | Dutch Eredivisie |
| 5 | Sun 1 Dec | 45-2 v FC UtrechtFC Utrecht 2-5 PSV Eindhoven | Dutch Eredivisie |
| 6 | Tue 21 Jan | 43-2 v Crvena ZvezdaCrvena Zvezda 2-3 PSV Eindhoven | UEFA Champions League Matchday 7 |
| 7 | Sat 25 Jan | 43-2 v NAC BredaPSV Eindhoven 3-2 NAC Breda | Dutch Eredivisie |
| 8 | Wed 29 Jan | 43-2 v LiverpoolPSV Eindhoven 3-2 Liverpool | UEFA Champions League Matchday 8 |
| 9 | Sat 1 Feb | 43-3 v NEC NijmegenNEC Nijmegen 3-3 PSV Eindhoven | Dutch Eredivisie |
| 10 | Sat 8 Feb | 41-1 v Willem IIPSV Eindhoven 1-1 Willem II | Dutch Eredivisie |
| 11 | Tue 11 Feb | 41-2 v JuventusJuventus 2-1 PSV Eindhoven | UEFA Champions League Play-off Knockout Round |
| 12 | Sat 15 Feb | 42-2 v FC UtrechtPSV Eindhoven 2-2 FC Utrecht | Dutch Eredivisie |
| 13 | Wed 19 Feb | 43-1 v JuventusPSV Eindhoven 3-1 Juventus | UEFA Champions League Play-off Knockout Round |
| 14 | Tue 4 Mar | 41-7 v ArsenalPSV Eindhoven 1-7 Arsenal | UEFA Champions League Round of 16 |
| 15 | Sat 8 Mar | 42-1 v sc HeerenveenPSV Eindhoven 2-1 sc Heerenveen | Dutch Eredivisie |
| 16 | Wed 12 Mar | 42-2 v ArsenalArsenal 2-2 PSV Eindhoven | UEFA Champions League Round of 16 |
| 17 | Thu 24 Apr | 4 3-1 v FC TwenteFC Twente 1-3 PSV Eindhoven | Dutch Eredivisie |
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