| 1 | Tue 8 Aug | 344-1 v Sturm GrazPSV Eindhoven 4-1 Sturm Graz | UEFA Champions League Third Qualifying Round |
| 2 | Sat 12 Aug | 342-0 v FC UtrechtPSV Eindhoven 2-0 FC Utrecht | Dutch Eredivisie |
| 3 | Tue 15 Aug | 343-1 v Sturm GrazSturm Graz 1-3 PSV Eindhoven | UEFA Champions League Third Qualifying Round |
| 4 | Sat 19 Aug | 343-1 v VitesseVitesse 1-3 PSV Eindhoven | Dutch Eredivisie |
| 5 | Tue 22 Aug | 342-2 v RangersRangers 2-2 PSV Eindhoven | UEFA Champions League Play-off Qualifying Play-off Round |
| 6 | Wed 30 Aug | 345-1 v RangersPSV Eindhoven 5-1 Rangers | UEFA Champions League Play-off Qualifying Play-off Round |
| 7 | Sat 2 Sep | 344-0 v RKC WaalwijkRKC Waalwijk 0-4 PSV Eindhoven | Dutch Eredivisie |
| 8 | Sat 16 Sep | 344-0 v NEC NijmegenPSV Eindhoven 4-0 NEC Nijmegen | Dutch Eredivisie |
| 9 | Wed 20 Sep | 340-4 v ArsenalArsenal 4-0 PSV Eindhoven | UEFA Champions League Group B |
| 10 | Wed 27 Sep | 343-0 v Go Ahead EaglesPSV Eindhoven 3-0 Go Ahead Eagles | Dutch Eredivisie |
| 11 | Sat 30 Sep | 343-1 v VolendamPSV Eindhoven 3-1 Volendam | Dutch Eredivisie |
| 12 | Tue 3 Oct | 342-2 v SevillaPSV Eindhoven 2-2 Sevilla | UEFA Champions League Group B |
| 13 | Sun 8 Oct | 344-0 v Sparta RotterdamSparta Rotterdam 0-4 PSV Eindhoven | Dutch Eredivisie |
| 14 | Tue 24 Oct | 341-1 v LensLens 1-1 PSV Eindhoven | UEFA Champions League Group B |
| 15 | Sun 29 Oct | 34 5-2 v AjaxPSV Eindhoven 5-2 Ajax | Dutch Eredivisie |
| 16 | Sat 4 Nov | 346-0 v Heracles AlmeloHeracles Almelo 0-6 PSV Eindhoven | Dutch Eredivisie |
| 17 | Wed 8 Nov | 341-0 v LensPSV Eindhoven 1-0 Lens | UEFA Champions League Group B |
| 18 | Sun 12 Nov | 344-0 v PEC ZwollePSV Eindhoven 4-0 PEC Zwolle | Dutch Eredivisie |
| 19 | Sat 25 Nov | 343-0 v FC TwenteFC Twente 0-3 PSV Eindhoven | Dutch Eredivisie |
| 20 | Wed 29 Nov | 343-2 v SevillaSevilla 2-3 PSV Eindhoven | UEFA Champions League Group B |
| 21 | Sun 3 Dec | 342-1 v FeyenoordFeyenoord 1-2 PSV Eindhoven | Dutch Eredivisie |
| 22 | Thu 7 Dec | 342-0 v sc HeerenveenPSV Eindhoven 2-0 sc Heerenveen | Dutch Eredivisie |
| 23 | Tue 12 Dec | 341-1 v ArsenalPSV Eindhoven 1-1 Arsenal | UEFA Champions League Group B |
| 24 | Sun 17 Dec | 344-0 v AZ AlkmaarAZ Alkmaar 0-4 PSV Eindhoven | Dutch Eredivisie |
| 25 | Sat 3 Feb | 341-1 v AjaxAjax 1-1 PSV Eindhoven | Dutch Eredivisie |
| 26 | Sun 11 Feb | 345-1 v VolendamVolendam 1-5 PSV Eindhoven | Dutch Eredivisie |
| 27 | Tue 20 Feb | 341-1 v Borussia DortmundPSV Eindhoven 1-1 Borussia Dortmund | UEFA Champions League Round of 16 |
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