| 1 | Tue 8 Aug | 144-1 v Sturm GrazPSV Eindhoven 4-1 Sturm Graz | UEFA Champions League Third Qualifying Round |
| 2 | Sat 12 Aug | 142-0 v FC UtrechtPSV Eindhoven 2-0 FC Utrecht | Dutch Eredivisie |
| 3 | Tue 15 Aug | 143-1 v Sturm GrazSturm Graz 1-3 PSV Eindhoven | UEFA Champions League Third Qualifying Round |
| 4 | Sat 2 Sep | 144-0 v RKC WaalwijkRKC Waalwijk 0-4 PSV Eindhoven | Dutch Eredivisie |
| 5 | Sat 9 Sep | 93-0 v UzbekistanUSA 3-0 Uzbekistan | International Friendly |
| 6 | Wed 13 Sep | 94-0 v OmanUSA 4-0 Oman | International Friendly |
| 7 | Sat 16 Sep | 144-0 v NEC NijmegenPSV Eindhoven 4-0 NEC Nijmegen | Dutch Eredivisie |
| 8 | Wed 20 Sep | 140-4 v ArsenalArsenal 4-0 PSV Eindhoven | UEFA Champions League Group B |
| 9 | Sat 23 Sep | 144-0 v Almere CityAlmere City 0-4 PSV Eindhoven | Dutch Eredivisie |
| 10 | Wed 27 Sep | 143-0 v Go Ahead EaglesPSV Eindhoven 3-0 Go Ahead Eagles | Dutch Eredivisie |
| 11 | Sat 30 Sep | 14 3-1 v VolendamPSV Eindhoven 3-1 Volendam | Dutch Eredivisie |
| 12 | Tue 3 Oct | 142-2 v SevillaPSV Eindhoven 2-2 Sevilla | UEFA Champions League Group B |
| 13 | Sat 14 Oct | 91-3 v GermanyUSA 1-3 Germany | International Friendly |
| 14 | Wed 18 Oct | 94-0 v GhanaUSA 4-0 Ghana | International Friendly |
| 15 | Sat 21 Oct | 143-1 v Fortuna SittardPSV Eindhoven 3-1 Fortuna Sittard | Dutch Eredivisie |
| 16 | Tue 24 Oct | 14 1-1 v LensLens 1-1 PSV Eindhoven | UEFA Champions League Group B |
| 17 | Sun 29 Oct | 145-2 v AjaxPSV Eindhoven 5-2 Ajax | Dutch Eredivisie |
| 18 | Sat 4 Nov | 146-0 v Heracles AlmeloHeracles Almelo 0-6 PSV Eindhoven | Dutch Eredivisie |
| 19 | Wed 8 Nov | 141-0 v LensPSV Eindhoven 1-0 Lens | UEFA Champions League Group B |
| 20 | Sun 12 Nov | 144-0 v PEC ZwollePSV Eindhoven 4-0 PEC Zwolle | Dutch Eredivisie |
| 21 | Sat 25 Nov | 143-0 v FC TwenteFC Twente 0-3 PSV Eindhoven | Dutch Eredivisie |
| 22 | Wed 29 Nov | 143-2 v SevillaSevilla 2-3 PSV Eindhoven | UEFA Champions League Group B |
| 23 | Thu 7 Dec | 14 2-0 v sc HeerenveenPSV Eindhoven 2-0 sc Heerenveen | Dutch Eredivisie |
| 24 | Tue 12 Dec | 141-1 v ArsenalPSV Eindhoven 1-1 Arsenal | UEFA Champions League Group B |
| 25 | Sun 17 Dec | 144-0 v AZ AlkmaarAZ Alkmaar 0-4 PSV Eindhoven | Dutch Eredivisie |
| 26 | Sat 13 Jan | 143-1 v Excelsior RotterdamPSV Eindhoven 3-1 Excelsior Rotterdam | Dutch Eredivisie |
| 27 | Sun 21 Jan | 141-1 v FC UtrechtFC Utrecht 1-1 PSV Eindhoven | Dutch Eredivisie |
| 28 | Sat 27 Jan | 142-0 v Almere CityPSV Eindhoven 2-0 Almere City | Dutch Eredivisie |
| 29 | Sun 11 Feb | 145-1 v VolendamVolendam 1-5 PSV Eindhoven | Dutch Eredivisie |
| 30 | Fri 16 Feb | 142-0 v Heracles AlmeloPSV Eindhoven 2-0 Heracles Almelo | Dutch Eredivisie |
| 31 | Tue 20 Feb | 141-1 v Borussia DortmundPSV Eindhoven 1-1 Borussia Dortmund | UEFA Champions League Round of 16 |
| 32 | Sat 24 Feb | 147-1 v PEC ZwollePEC Zwolle 1-7 PSV Eindhoven | Dutch Eredivisie |
| 33 | Fri 8 Mar | 141-0 v Go Ahead EaglesGo Ahead Eagles 0-1 PSV Eindhoven | Dutch Eredivisie |
| 34 | Wed 13 Mar | 140-2 v Borussia DortmundBorussia Dortmund 2-0 PSV Eindhoven | UEFA Champions League Round of 16 |
| 35 | Sun 17 Mar | 141-0 v FC TwentePSV Eindhoven 1-0 FC Twente | Dutch Eredivisie |
| 36 | Sat 30 Mar | 141-3 v NEC NijmegenNEC Nijmegen 3-1 PSV Eindhoven | Dutch Eredivisie |
| 37 | Tue 2 Apr | 142-0 v Excelsior RotterdamExcelsior Rotterdam 0-2 PSV Eindhoven | Dutch Eredivisie |
| 38 | Thu 25 Apr | 148-0 v sc Heerenveensc Heerenveen 0-8 PSV Eindhoven | Dutch Eredivisie |
| 39 | Sun 5 May | 144-2 v Sparta RotterdamPSV Eindhoven 4-2 Sparta Rotterdam | Dutch Eredivisie |
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