| 1 | Sun 13 Aug | 161-2 v Real BetisVillarreal 1-2 Real Betis | Spanish La Liga |
| 2 | Fri 18 Aug | 16 1-0 v MallorcaMallorca 0-1 Villarreal | Spanish La Liga |
| 3 | Sun 27 Aug | 163-4 v BarcelonaVillarreal 3-4 Barcelona | Spanish La Liga |
| 4 | Fri 1 Sep | 16 1-3 v CádizCádiz 3-1 Villarreal | Spanish La Liga |
| 5 | Tue 12 Sep | 176-0 v CyprusSpain 6-0 Cyprus | European Championship Qualification Group A |
| 6 | Sun 17 Sep | 162-1 v AlmeríaVillarreal 2-1 Almería | Spanish La Liga |
| 7 | Thu 21 Sep | 16 0-2 v PanathinaikosPanathinaikos 2-0 Villarreal | UEFA Europa League Group F |
| 8 | Sun 24 Sep | 161-1 v Rayo VallecanoRayo Vallecano 1-1 Villarreal | Spanish La Liga |
| 9 | Wed 27 Sep | 16 1-2 v GironaVillarreal 1-2 Girona | Spanish La Liga |
| 10 | Sat 30 Sep | 16 0-0 v GetafeGetafe 0-0 Villarreal | Spanish La Liga |
| 11 | Thu 5 Oct | 16 1-0 v RennesVillarreal 1-0 Rennes | UEFA Europa League Group F |
| 12 | Mon 30 Oct | 16 3-2 v GranadaGranada 2-3 Villarreal | Spanish La Liga |
| 13 | Sun 5 Nov | 162-3 v Athletic BilbaoVillarreal 2-3 Athletic Bilbao | Spanish La Liga |
| 14 | Thu 9 Nov | 162-1 v Maccabi HaifaMaccabi Haifa 1-2 Villarreal | UEFA Europa League Group F |
| 15 | Sun 12 Nov | 161-3 v Atlético MadridAtlético Madrid 3-1 Villarreal | Spanish La Liga |
| 16 | Sun 26 Nov | 163-1 v OsasunaVillarreal 3-1 Osasuna | Spanish La Liga |
| 17 | Thu 30 Nov | 163-2 v PanathinaikosVillarreal 3-2 Panathinaikos | UEFA Europa League Group F |
| 18 | Sun 3 Dec | 161-1 v SevillaSevilla 1-1 Villarreal | Spanish La Liga |
| 19 | Wed 6 Dec | 160-0 v Maccabi HaifaVillarreal 0-0 Maccabi Haifa | UEFA Europa League Group F |
| 20 | Sat 9 Dec | 160-3 v Real SociedadVillarreal 0-3 Real Sociedad | Spanish La Liga |
| 21 | Thu 14 Dec | 163-2 v RennesRennes 2-3 Villarreal | UEFA Europa League Group F |
| 22 | Sun 17 Dec | 161-4 v Real MadridReal Madrid 4-1 Villarreal | Spanish La Liga |
| 23 | Wed 20 Dec | 16 3-2 v Celta VigoVillarreal 3-2 Celta Vigo | Spanish La Liga |
| 24 | Sat 13 Jan | 16 0-3 v Las PalmasLas Palmas 3-0 Villarreal | Spanish La Liga |
| 25 | Sat 20 Jan | 161-1 v MallorcaVillarreal 1-1 Mallorca | Spanish La Liga |
| 26 | Sat 27 Jan | 16 5-3 v BarcelonaBarcelona 3-5 Villarreal | Spanish La Liga |
| 27 | Sun 4 Feb | 16 0-0 v CádizVillarreal 0-0 Cádiz | Spanish La Liga |
| 28 | Sat 10 Feb | 161-1 v AlavésAlavés 1-1 Villarreal | Spanish La Liga |
| 29 | Fri 16 Feb | 161-1 v GetafeVillarreal 1-1 Getafe | Spanish La Liga |
| 30 | Fri 23 Feb | 163-1 v Real SociedadReal Sociedad 1-3 Villarreal | Spanish La Liga |
| 31 | Sun 3 Mar | 165-1 v GranadaVillarreal 5-1 Granada | Spanish La Liga |
| 32 | Thu 7 Mar | 160-4 v MarseilleMarseille 4-0 Villarreal | UEFA Europa League Round of 16 |
| 33 | Sun 10 Mar | 163-2 v Real BetisReal Betis 2-3 Villarreal | Spanish La Liga |
| 34 | Thu 14 Mar | 16 3-1 v MarseilleVillarreal 3-1 Marseille | UEFA Europa League Round of 16 |
| 35 | Sun 17 Mar | 16 1-0 v ValenciaVillarreal 1-0 Valencia | Spanish La Liga |
| 36 | Fri 22 Mar | 150-1 v ColombiaSpain 0-1 Colombia | International Friendly |
| 37 | Mon 1 Apr | 161-2 v Atlético MadridVillarreal 1-2 Atlético Madrid | Spanish La Liga |
| 38 | Sun 14 Apr | 161-1 v Athletic BilbaoAthletic Bilbao 1-1 Villarreal | Spanish La Liga |
| 39 | Sun 21 Apr | 162-1 v AlmeríaAlmería 1-2 Villarreal | Spanish La Liga |
| 40 | Sun 28 Apr | 163-0 v Rayo VallecanoVillarreal 3-0 Rayo Vallecano | Spanish La Liga |
| 41 | Sun 5 May | 162-3 v Celta VigoCelta Vigo 3-2 Villarreal | Spanish La Liga |
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